Thermal Isomerization of α-Pinene in Supercritical Ethanol Full article
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Chemical Engineering Science
ISSN: 0009-2509 , E-ISSN: 1873-4405 |
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| Output data | Year: 2007, Volume: 62, Number: 9, Pages: 2414-2421 Pages count : 8 DOI: 10.1016/j.ces.2007.01.041 | ||||
| Tags | α-pinene, Kinetic model, Model identification, Pressure effect, Supercritical solvents-fluids, Terpene compounds, Transition state | ||||
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Abstract:
The experimental study followed by mathematical processing of the data showed that supercritical ethanol is an effective reaction medium for thermal isomerization of α-pinene. Rate of the reaction in supercritical solvent is by several orders of magnitude greater than the rate observed under normal conditions, with selectivity to the target reaction products being retained. The study allowed us for the first time to obtain the kinetic model of α-pinene isomerization in supercritical ethanol that takes into account temperature and pressure effect on the reaction rate and selectivity.
Cite:
Yermakova A.
, Chibiryaev A.M.
, Kozhevnikov I.V.
, Mikenin P.E.
, Anikeev V.I.
Thermal Isomerization of α-Pinene in Supercritical Ethanol
Chemical Engineering Science. 2007. V.62. N9. P.2414-2421. DOI: 10.1016/j.ces.2007.01.041 WOS Scopus РИНЦ OpenAlex ANCAN
Thermal Isomerization of α-Pinene in Supercritical Ethanol
Chemical Engineering Science. 2007. V.62. N9. P.2414-2421. DOI: 10.1016/j.ces.2007.01.041 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Apr 10, 2006 |
| Accepted: | Jan 19, 2007 |
| Published online: | Feb 4, 2007 |
| Published print: | May 1, 2007 |
Identifiers:
| ≡ Web of science: | WOS:000246492900010 |
| ≡ Scopus: | 2-s2.0-33947668295 |
| ≡ Elibrary: | 13554271 |
| ≡ OpenAlex: | W2071431371 |
| ≡ Chemical Abstracts: | 2007:367320 |
| ≡ Chemical Abstracts (print): | 146:523760 |