Combinatorial Approach to the Preparation and Characterization of Catalysts for Biomass Steam Reforming into Syngas | Sciact - CRIS-система Института катализа

Combinatorial Approach to the Preparation and Characterization of Catalysts for Biomass Steam Reforming into Syngas Научная публикация

Конференция

European Conference on Combinatorial Catalysis Research
22-25 апр. 2007 , Bari

Журнал

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Вых. Данные

Год: 2008, Том: 137, Номер: 1, Страницы: 23-28 Страниц : 6 DOI: 10.1016/j.cattod.2008.03.016

Ключевые слова

Bio-oil, Ce-Zr mixed oxides, Combinatorial synthesis, Cu-Ni, Pt, Ru, Steam reforming of ethanol, Syngas

Авторы

Yaseneva Polina ¹ , Pavlova Svetlana ¹ , Sadykov Vladislav ¹ , Alikina Galina ¹ , Lukashevich Anton ¹ , Rogov Vladimir ¹ , Beloshapkin Sergey ² , Ross Julian ³

Организации

1	Boreskov Institute of Catalysis, 5, Pr. Lavrentieva, 630090 Novosibirsk, Russia
2	Materials & Surface Science Institute, University of Limerick, Limerick, Ireland
3	Centre of Environmental Research, University of Limerick, Limerick, Ireland

Информация о финансировании (1)

International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union

05-1000005-7663

A number of catalysts based on Al2O3 loaded with doped Ce-Zr mixed oxides and different active components (Cu, Cu-Ni, Ru, Pt, etc.) were synthesized via standard wet impregnation method using the robotic workstation. Ethanol (EtOH) was taken as a model compound of bio-oil and steam reforming of ethanol (ESR)—as a model reaction. Activity screening experiments performed at 600–700 °C in 0.5 vol.% C2H5OH + 2.5 vol.% H2O + 97 vol.% He mixture revealed that the most effective catalyst composition is Ru/Ce0.4Zr0.4Sm0.2/Al2O3. Catalytic activity investigations at high reagent concentrations (10 vol.% C2H5OH + 40 vol.% H2O + 50 vol.% N2) at 650–800 °C confirmed this fact, revealing also that at high temperatures the activity of Cu-Ni catalysts is comparable with that of Ru-containing catalyst.

Yaseneva P. , Pavlova S. , Sadykov V. , Alikina G. , Lukashevich A. , Rogov V. , Beloshapkin S. , Ross J.
Combinatorial Approach to the Preparation and Characterization of Catalysts for Biomass Steam Reforming into Syngas
Catalysis Today. 2008. V.137. N1. P.23-28. DOI: 10.1016/j.cattod.2008.03.016 WOS Scopus РИНЦ CAPlusCA OpenAlex

Опубликована online:	15 мая 2008 г.
Опубликована в печати:	30 авг. 2008 г.

Web of science:	WOS:000258060900005
Scopus:	2-s2.0-45949108895
РИНЦ:	13575531
Chemical Abstracts:	2008:798360
Chemical Abstracts (print):	149:311163
OpenAlex:	W2045544692

БД	Цитирований
Web of science	25
Scopus	31
РИНЦ	29
OpenAlex	25