Combinatorial Approach to the Preparation and Characterization of Catalysts for Biomass Steam Reforming into Syngas Full article
| Conference |
European Conference on Combinatorial Catalysis Research 22-25 Apr 2007 , Bari |
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| Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Output data | Year: 2008, Volume: 137, Number: 1, Pages: 23-28 Pages count : 6 DOI: 10.1016/j.cattod.2008.03.016 | ||||||
| Tags | Bio-oil, Ce-Zr mixed oxides, Combinatorial synthesis, Cu-Ni, Pt, Ru, Steam reforming of ethanol, Syngas | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | 05-1000005-7663 |
Abstract:
A number of catalysts based on Al2O3 loaded with doped Ce-Zr mixed oxides and different active components (Cu, Cu-Ni, Ru, Pt, etc.) were synthesized via standard wet impregnation method using the robotic workstation. Ethanol (EtOH) was taken as a model compound of bio-oil and steam reforming of ethanol (ESR)—as a model reaction. Activity screening experiments performed at 600–700 °C in 0.5 vol.% C2H5OH + 2.5 vol.% H2O + 97 vol.% He mixture revealed that the most effective catalyst composition is Ru/Ce0.4Zr0.4Sm0.2/Al2O3. Catalytic activity investigations at high reagent concentrations (10 vol.% C2H5OH + 40 vol.% H2O + 50 vol.% N2) at 650–800 °C confirmed this fact, revealing also that at high temperatures the activity of Cu-Ni catalysts is comparable with that of Ru-containing catalyst.
Cite:
Yaseneva P.
, Pavlova S.
, Sadykov V.
, Alikina G.
, Lukashevich A.
, Rogov V.
, Beloshapkin S.
, Ross J.
Combinatorial Approach to the Preparation and Characterization of Catalysts for Biomass Steam Reforming into Syngas
Catalysis Today. 2008. V.137. N1. P.23-28. DOI: 10.1016/j.cattod.2008.03.016 WOS Scopus РИНЦ ANCAN OpenAlex
Combinatorial Approach to the Preparation and Characterization of Catalysts for Biomass Steam Reforming into Syngas
Catalysis Today. 2008. V.137. N1. P.23-28. DOI: 10.1016/j.cattod.2008.03.016 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | May 15, 2008 |
| Published print: | Aug 30, 2008 |
Identifiers:
| Web of science: | WOS:000258060900005 |
| Scopus: | 2-s2.0-45949108895 |
| Elibrary: | 13575531 |
| Chemical Abstracts: | 2008:798360 |
| Chemical Abstracts (print): | 149:311163 |
| OpenAlex: | W2045544692 |