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Oxide Catalysts for Ammonia Oxidation in Nitric Acid Production: Properties and Perspectives Обзор

Журнал Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Вых. Данные Год: 2000, Том: 204, Номер: 1, Страницы: 59-87 Страниц : 29 DOI: 10.1016/S0926-860X(00)00506-8, 10.1002/chin.200102248
Ключевые слова Ammonia oxidation; Nitric acid production; Oxide catalysts; Honeycomb monoliths; Perovskites
Авторы Sadykov V.A. 1 , Isupova L.A. 1 , Zolotarskii I.A. 1 , Bobrova L.N. 1 , Noskov A.S. 1 , Parmon V.N. 1 , Brushtein E.A. 2 , Telyatnikova T.V. 2 , Chernyshev V.I. 2 , Lunin V.V. 3
Организации
1 The Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences
2 Joint Stock Venture ‘State Institute of Nitrogen Industry (GIAP)’
3 The Lomonosov Moscow State University

Реферат: This paper generalizes the results of long-term efforts aimed at research and development of industrial oxide catalysts for ammonia oxidation in the nitric acid production within two-bed (Pt gauzes+monolithic oxide layers) technology of the high pressure process. Main factors determining performance of precious metals and oxides in the high-temperature ammonia oxidation are considered. The surface oxygen bonding strength determined by the surface atomic structure appears to be the most important. From this point of view, existing approaches to synthesis of mixed oxide systems including perovskites with controlled nitric oxide selectivity and good stability in the high-temperature process of ammonia oxidation are analyzed. Main features of the bulk oxide monolithic catalysts production technology and principles of a two-bed system design based upon the process mathematical modeling are briefly outlined. Proven economic benefits of this technology recently commercialized in Russia at nitric acid plants are debated.
Библиографическая ссылка: Sadykov V.A. , Isupova L.A. , Zolotarskii I.A. , Bobrova L.N. , Noskov A.S. , Parmon V.N. , Brushtein E.A. , Telyatnikova T.V. , Chernyshev V.I. , Lunin V.V.
Oxide Catalysts for Ammonia Oxidation in Nitric Acid Production: Properties and Perspectives
Applied Catalysis A: General. 2000. V.204. N1. P.59-87. DOI: 10.1016/S0926-860X(00)00506-8, 10.1002/chin.200102248 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 28 апр. 1999 г.
Принята к публикации: 29 февр. 2000 г.
Опубликована online: 15 сент. 2000 г.
Опубликована в печати: 6 нояб. 2000 г.
Идентификаторы БД:
Web of science: WOS:000090028500006
Scopus: 2-s2.0-0034310804
РИНЦ: 13349100
Chemical Abstracts: 2000:658839
Chemical Abstracts (print): 133:314175
OpenAlex: W2092891954
Цитирование в БД:
БД Цитирований
Web of science 95
Scopus 106
РИНЦ 109
OpenAlex 111
Альметрики: