Oxide Catalysts for Ammonia Oxidation in Nitric Acid Production: Properties and Perspectives | Sciact - CRIS-system of Boreskov Institute of Catalysis

Oxide Catalysts for Ammonia Oxidation in Nitric Acid Production: Properties and Perspectives Review

Journal

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Output data

Year: 2000, Volume: 204, Number: 1, Pages: 59-87 Pages count : 29 DOI: 10.1016/S0926-860X(00)00506-8, 10.1002/chin.200102248

Tags

Ammonia oxidation; Nitric acid production; Oxide catalysts; Honeycomb monoliths; Perovskites

Authors

Sadykov V.A. ¹ , Isupova L.A. ¹ , Zolotarskii I.A. ¹ , Bobrova L.N. ¹ , Noskov A.S. ¹ , Parmon V.N. ¹ , Brushtein E.A. ² , Telyatnikova T.V. ² , Chernyshev V.I. ² , Lunin V.V. ³

Affiliations

1	The Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences
2	Joint Stock Venture ‘State Institute of Nitrogen Industry (GIAP)’
3	The Lomonosov Moscow State University

This paper generalizes the results of long-term efforts aimed at research and development of industrial oxide catalysts for ammonia oxidation in the nitric acid production within two-bed (Pt gauzes+monolithic oxide layers) technology of the high pressure process. Main factors determining performance of precious metals and oxides in the high-temperature ammonia oxidation are considered. The surface oxygen bonding strength determined by the surface atomic structure appears to be the most important. From this point of view, existing approaches to synthesis of mixed oxide systems including perovskites with controlled nitric oxide selectivity and good stability in the high-temperature process of ammonia oxidation are analyzed. Main features of the bulk oxide monolithic catalysts production technology and principles of a two-bed system design based upon the process mathematical modeling are briefly outlined. Proven economic benefits of this technology recently commercialized in Russia at nitric acid plants are debated.

Sadykov V.A. , Isupova L.A. , Zolotarskii I.A. , Bobrova L.N. , Noskov A.S. , Parmon V.N. , Brushtein E.A. , Telyatnikova T.V. , Chernyshev V.I. , Lunin V.V.
Oxide Catalysts for Ammonia Oxidation in Nitric Acid Production: Properties and Perspectives
Applied Catalysis A: General. 2000. V.204. N1. P.59-87. DOI: 10.1016/S0926-860X(00)00506-8, 10.1002/chin.200102248 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Apr 28, 1999
Accepted:	Feb 29, 2000
Published online:	Sep 15, 2000
Published print:	Nov 6, 2000

Web of science:	WOS:000090028500006
Scopus:	2-s2.0-0034310804
Elibrary:	13349100
Chemical Abstracts:	2000:658839
Chemical Abstracts (print):	133:314175
OpenAlex:	W2092891954

DB	Citing
Web of science	94
Scopus	105
Elibrary	108
OpenAlex	109