Fenton Degradation of Sulfanilamide in the Presence of Al,Fe-Pillared Clay: Catalytic Behaviour and Identification of the Intermediates | Sciact - CRIS-system of Boreskov Institute of Catalysis

Fenton Degradation of Sulfanilamide in the Presence of Al,Fe-Pillared Clay: Catalytic Behaviour and Identification of the Intermediates Full article

Journal

Journal of Hazardous Materials
ISSN: 0304-3894 , E-ISSN: 1873-3336

Output data

Year: 2015, Volume: 293, Pages: 21-29 Pages count : 9 DOI: 10.1016/j.jhazmat.2015.03.038

Tags

Degradation intermediates, Hydrogen peroxide, Oxidation, Pillared clays, Sulfanilamide

Authors

Khankhasaeva Sesegma Ts. ^1,2 , Dambueva Darima V. ¹ , Dashinamzhilova Elvira Ts. ¹ , Gil Antonio ³ , Vicente Miguel A. ⁴ , Timofeeva Maria N. ^5,6,7

Affiliations

1	Baikal Institute of Nature Management SB RAS, Str. Sakh’yanova 8, 670047 Ulan-Ude, Russian Federation
2	Buryat State University, Str. Smolina 24a, 670000 Ulan-Ude, Russian Federation
3	Department of Applied Chemistry, Public University of Navarra, 31006 Pamplona, Spain
4	Department of Inorganic Chemistry, University of Salamanca, Salamanca, Spain
5	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
6	Novosibirsk State University, St. Pirogova 2, 630090 Novosibirsk, Russian Federation
7	Novosibirsk State Technical University, Prospekt K. Marksa 20, 630092 Novosibirsk, Russian Federation

Funding (5)

1	Federal Agency for Scientific Organizations	V.44.2.12.
2	Federal Agency for Scientific Organizations	V.46.5.1.
3	Ministry of Economic Affairs and Digital Transformation	MAT2013-47811-C2-1-R, MAT2013-47811-C2-2-R
4	The Ministry of Education and Science of the Russian Federation
5	Ministry of Economic Affairs and Digital Transformation

Liquid phase catalytic degradation of sulfanilamide with H2O2 was carried out in the presence of Fe,Al/M-pillared clay (Fe,Al/M-MM, M = Na+, Ca2+and Ba2+) as heterogeneous Fenton type catalyst. Fe,Al/M-MMswere prepared by swelling of layered aluminosilicate (90–95 wt.% montmorillonite) from a bed locatedin Mukhortala (Buryatia, Russia) in Na+, Ca2+and Ba2+forms by means of the exchange of these cationswith bulky Fe,Al-polyoxocations prepared at Al/Fe = 10/1 and OH/(Al + Fe) = 2.0, and then calcinated at500◦C. XRD method and chemical analysis demonstrated that the rate of crystalline swelling was depen-dent on the interlayer cations and decreased in the order: Fe,Al-/Na-MM > Fe,Al/Ca-MM > Fe,Al/Ba-MM.It was found that the catalytic properties of Fe,Al/M-MMs depended on the type of exchangeable cations

Khankhasaeva S.T. , Dambueva D.V. , Dashinamzhilova E.T. , Gil A. , Vicente M.A. , Timofeeva M.N.
Fenton Degradation of Sulfanilamide in the Presence of Al,Fe-Pillared Clay: Catalytic Behaviour and Identification of the Intermediates
Journal of Hazardous Materials. 2015. V.293. P.21-29. DOI: 10.1016/j.jhazmat.2015.03.038 WOS Scopus РИНЦ ANCAN PMID OpenAlex

Submitted:	Nov 20, 2014
Accepted:	Mar 12, 2015
Published online:	Mar 19, 2015
Published print:	Aug 1, 2015

Web of science:	WOS:000355043000004
Scopus:	2-s2.0-84925440324
Elibrary:	24019638
Chemical Abstracts:	2015:486928
Chemical Abstracts (print):	162:453778
PMID:	25819990
OpenAlex:	W1965510716

DB	Citing
Web of science	52
Scopus	57
Elibrary	59
OpenAlex	58