Structured Nanocomposite Catalysts of Biofuels Transformation into Syngas and Hydrogen: Design and Performance | Sciact - CRIS-система Института катализа

Structured Nanocomposite Catalysts of Biofuels Transformation into Syngas and Hydrogen: Design and Performance Научная публикация

Журнал

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Вых. Данные

Год: 2015, Том: 40, Страницы: 7511-7522 Страниц : 12 DOI: 10.1016/j.ijhydene.2014.11.151

Ключевые слова

Biofuels reforming, Catalytic performance, Coking stability, Hydrogen and syngas, Microchannel and foam substrates, Nanocomposite active components

Авторы

Sadykov V. ^1,2 , Mezentseva N. ^1,2 , Simonov M. ^1,2 , Smal E. ^1,2 , Arapova M. ^1,2 , Pavlova S. ¹ , Fedorova Y. ¹ , Chub O. ¹ , Bobrova L. ¹ , Kuzmin V. ¹ , Ishchenko A. ^1,2 , Krieger T. ¹ , Roger A.-C. ³ , Parkhomenko K. ³ , Mirodatos C. ⁴ , Smorygo O. ⁵ , Ross J. ⁶

Организации

1	Boreskov Institute of Catalysis, Prosp. Lavrentieva, 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Novosibirsk, 630090, Russia
3	University of Strasbourg, Strasbourg, France
4	IRCELyon, Lyon, France
5	Institute of Powder Metallurgy, Minsk, Belarus
6	University of Limerick, Limerick, Ireland

Информация о финансировании (4)

1	Российский фонд фундаментальных исследований	12-03-93115
2	European Commission	228953 FP7-NMP-2008-LARGE-2 OCMOL
3	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO
4	Министерство образования и науки Российской Федерации

Main features of structured catalysts performance in bio-fuels reforming into syngas at lab-scale and pilot-scale levels using specially designed reactors and kinetic installations allowing to broadly tune the operational parameters are presented. Effects of the nature of nanocomposite active component comprised of RuþNi nanoparticles on bulk/aluminasupported perovskite or MneCreO spinel, type of substrate (Ni-Al alloy and SiC(Al2O3)/Al-Si-O foam substrates, Fechraloy microchannel plates or gauzes protected by thin corundum layer), type of fuel (natural gas, ethanol, acetone, ethyl acetate glycerol), feed composition and temperature on yield of syngas/byproducts and performance stability are considered. The best performance in real feeds with syngas yield approaching equilibrium at short contact times without any heat/mass transfer effects along with a high thermochemical stability were demonstrated for catalyst on heat-conducting microchannel substrate. Oxygen addition to the feed in optimized amounts allows to suppress coking and stabilize performance even for the case of such reactive fuel as glycerol only slightly affecting syngas yield.

Sadykov V. , Mezentseva N. , Simonov M. , Smal E. , Arapova M. , Pavlova S. , Fedorova Y. , Chub O. , Bobrova L. , Kuzmin V. , Ishchenko A. , Krieger T. , Roger A.-C. , Parkhomenko K. , Mirodatos C. , Smorygo O. , Ross J.
Structured Nanocomposite Catalysts of Biofuels Transformation into Syngas and Hydrogen: Design and Performance
International Journal of Hydrogen Energy. 2015. V.40. P.7511-7522. DOI: 10.1016/j.ijhydene.2014.11.151 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	30 авг. 2014 г.
Принята к публикации:	20 нояб. 2014 г.
Опубликована online:	19 янв. 2015 г.
Опубликована в печати:	1 июн. 2015 г.

Web of science:	WOS:000356549000012
Scopus:	2-s2.0-84930378540
РИНЦ:	24042664
Chemical Abstracts:	2015:100735
Chemical Abstracts (print):	162:631040
OpenAlex:	W2070559431

БД	Цитирований
Web of science	25
Scopus	25
РИНЦ	26
OpenAlex	25