Structured Nanocomposite Catalysts of Biofuels Transformation into Syngas and Hydrogen: Design and Performance | Sciact - CRIS-system of Boreskov Institute of Catalysis

Structured Nanocomposite Catalysts of Biofuels Transformation into Syngas and Hydrogen: Design and Performance Full article

Journal

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Output data

Year: 2015, Volume: 40, Pages: 7511-7522 Pages count : 12 DOI: 10.1016/j.ijhydene.2014.11.151

Tags

Biofuels reforming, Catalytic performance, Coking stability, Hydrogen and syngas, Microchannel and foam substrates, Nanocomposite active components

Authors

Sadykov V. ^1,2 , Mezentseva N. ^1,2 , Simonov M. ^1,2 , Smal E. ^1,2 , Arapova M. ^1,2 , Pavlova S. ¹ , Fedorova Y. ¹ , Chub O. ¹ , Bobrova L. ¹ , Kuzmin V. ¹ , Ishchenko A. ^1,2 , Krieger T. ¹ , Roger A.-C. ³ , Parkhomenko K. ³ , Mirodatos C. ⁴ , Smorygo O. ⁵ , Ross J. ⁶

Affiliations

1	Boreskov Institute of Catalysis, Prosp. Lavrentieva, 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Novosibirsk, 630090, Russia
3	University of Strasbourg, Strasbourg, France
4	IRCELyon, Lyon, France
5	Institute of Powder Metallurgy, Minsk, Belarus
6	University of Limerick, Limerick, Ireland

Funding (4)

1	Russian Foundation for Basic Research	12-03-93115
2	European Commission	228953 FP7-NMP-2008-LARGE-2 OCMOL
3	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO
4	The Ministry of Education and Science of the Russian Federation

Main features of structured catalysts performance in bio-fuels reforming into syngas at lab-scale and pilot-scale levels using specially designed reactors and kinetic installations allowing to broadly tune the operational parameters are presented. Effects of the nature of nanocomposite active component comprised of RuþNi nanoparticles on bulk/aluminasupported perovskite or MneCreO spinel, type of substrate (Ni-Al alloy and SiC(Al2O3)/Al-Si-O foam substrates, Fechraloy microchannel plates or gauzes protected by thin corundum layer), type of fuel (natural gas, ethanol, acetone, ethyl acetate glycerol), feed composition and temperature on yield of syngas/byproducts and performance stability are considered. The best performance in real feeds with syngas yield approaching equilibrium at short contact times without any heat/mass transfer effects along with a high thermochemical stability were demonstrated for catalyst on heat-conducting microchannel substrate. Oxygen addition to the feed in optimized amounts allows to suppress coking and stabilize performance even for the case of such reactive fuel as glycerol only slightly affecting syngas yield.

Sadykov V. , Mezentseva N. , Simonov M. , Smal E. , Arapova M. , Pavlova S. , Fedorova Y. , Chub O. , Bobrova L. , Kuzmin V. , Ishchenko A. , Krieger T. , Roger A.-C. , Parkhomenko K. , Mirodatos C. , Smorygo O. , Ross J.
Structured Nanocomposite Catalysts of Biofuels Transformation into Syngas and Hydrogen: Design and Performance
International Journal of Hydrogen Energy. 2015. V.40. P.7511-7522. DOI: 10.1016/j.ijhydene.2014.11.151 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 30, 2014
Accepted:	Nov 20, 2014
Published online:	Jan 19, 2015
Published print:	Jun 1, 2015

Web of science:	WOS:000356549000012
Scopus:	2-s2.0-84930378540
Elibrary:	24042664
Chemical Abstracts:	2015:100735
Chemical Abstracts (print):	162:631040
OpenAlex:	W2070559431

DB	Citing
Web of science	25
Scopus	25
Elibrary	26
OpenAlex	26