Bioinspired Oxidations of Aliphatic C–H Groups with H2O2 in the Presence of Manganese Complexes | Sciact - CRIS-система Института катализа

Bioinspired Oxidations of Aliphatic C–H Groups with H2O2 in the Presence of Manganese Complexes Обзор

Журнал

Journal of Organometallic Chemistry
ISSN: 0022-328X

Вых. Данные

Год: 2015, Том: 793, Страницы: 102-107 Страниц : 6 DOI: 10.1016/j.jorganchem.2014.12.014

Ключевые слова

Biomimetic catalysis, Hydrogen peroxide, Intermediate, Manganese, Mechanism, Oxidation

Авторы

Talsi Evgenii P. ^1,2 , Ottenbacher Roman V. ^1,2 , Bryliakov Konstantin P. ^1,2

Организации

1	Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russian Federation
2	Novosibirsk State University, ul. Pirogova 2, Novosibirsk 630090, Russian Federation

Информация о финансировании (1)

Российский научный фонд

14-13-00158

In this paper, the progress of selective oxidation of aliphatic C–H groups with H2O2 in the presence of bioinspired manganese complexes, from 1990s until present days, is overviewed. Major milestones in catalysts development, as well as practical issues, such as efficiency, regio- and stereoselectivity, are discussed. Possible mechanism of predictably selective (non-radical) C–H oxidations over novel aminopyridine manganese complexes is considered.

Talsi E.P. , Ottenbacher R.V. , Bryliakov K.P.
Bioinspired Oxidations of Aliphatic C–H Groups with H2O2 in the Presence of Manganese Complexes
Journal of Organometallic Chemistry. 2015. V.793. P.102-107. DOI: 10.1016/j.jorganchem.2014.12.014 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	11 нояб. 2014 г.
Принята к публикации:	11 дек. 2014 г.
Опубликована online:	19 дек. 2014 г.
Опубликована в печати:	1 сент. 2015 г.

Web of science:	WOS:000360026000011
Scopus:	2-s2.0-84939491618
РИНЦ:	24419753
Chemical Abstracts:	2015:20279
Chemical Abstracts (print):	163:283244
OpenAlex:	W2082056891

БД	Цитирований
Web of science	30
Scopus	34
РИНЦ	32
OpenAlex	36