Bioinspired Oxidations of Aliphatic C–H Groups with H2O2 in the Presence of Manganese Complexes Review
| Journal |
Journal of Organometallic Chemistry
ISSN: 0022-328X |
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| Output data | Year: 2015, Volume: 793, Pages: 102-107 Pages count : 6 DOI: 10.1016/j.jorganchem.2014.12.014 | ||||
| Tags | Biomimetic catalysis, Hydrogen peroxide, Intermediate, Manganese, Mechanism, Oxidation | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-13-00158 |
Abstract:
In this paper, the progress of selective oxidation of aliphatic C–H groups with H2O2 in the presence of bioinspired manganese complexes, from 1990s until present days, is overviewed. Major milestones in catalysts development, as well as practical issues, such as efficiency, regio- and stereoselectivity, are discussed. Possible mechanism of predictably selective (non-radical) C–H oxidations over novel aminopyridine manganese complexes is considered.
Cite:
Talsi E.P.
, Ottenbacher R.V.
, Bryliakov K.P.
Bioinspired Oxidations of Aliphatic C–H Groups with H2O2 in the Presence of Manganese Complexes
Journal of Organometallic Chemistry. 2015. V.793. P.102-107. DOI: 10.1016/j.jorganchem.2014.12.014 WOS Scopus РИНЦ OpenAlex ANCAN
Bioinspired Oxidations of Aliphatic C–H Groups with H2O2 in the Presence of Manganese Complexes
Journal of Organometallic Chemistry. 2015. V.793. P.102-107. DOI: 10.1016/j.jorganchem.2014.12.014 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Nov 11, 2014 |
| Accepted: | Dec 11, 2014 |
| Published online: | Dec 19, 2014 |
| Published print: | Sep 1, 2015 |
Identifiers:
| ≡ Web of science: | WOS:000360026000011 |
| ≡ Scopus: | 2-s2.0-84939491618 |
| ≡ Elibrary: | 24419753 |
| ≡ OpenAlex: | W2082056891 |
| ≡ Chemical Abstracts: | 2015:20279 |
| ≡ Chemical Abstracts (print): | 163:283244 |