Gas Phase Epoxidation of Propylene with CO/O2 Mixture on Au/TiO2 Научная публикация
| Журнал |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
||||
|---|---|---|---|---|---|
| Вых. Данные | Год: 2013, Том: 40, Страницы: 103-105 Страниц : 3 DOI: 10.1016/j.catcom.2013.06.019 | ||||
| Ключевые слова | Propylene oxide; Epoxidation; CO/O2 mixture; Gold catalysts; Au/TiO2 | ||||
| Авторы |
|
||||
| Организации |
|
Реферат:
As it is known, propylene is able to react with H-2/O-2 mixture over gold particles supported on titania to give selectively propylene oxide. In the present work, similar epoxidation of propylene is achieved through the use of CO instead of hydrogen as the reduction agent. The propylene oxide yield goes through the maximum as a function of reaction time, the maximal value being twice higher compared to the yield of propylene oxide attained by "traditional" reaction with H-2/O-2 mixture. The propylene oxide selectivity attains 93% at propylene conversion of 2%. Utilization efficiency of CO reaches 25%, which is comparable to that of H-2.
Библиографическая ссылка:
Sobolev V.I.
, Koltunov K.Y.
Gas Phase Epoxidation of Propylene with CO/O2 Mixture on Au/TiO2
Catalysis Communications. 2013. V.40. P.103-105. DOI: 10.1016/j.catcom.2013.06.019 WOS Scopus РИНЦ РИНЦ OpenAlex CAPlusCA
Gas Phase Epoxidation of Propylene with CO/O2 Mixture on Au/TiO2
Catalysis Communications. 2013. V.40. P.103-105. DOI: 10.1016/j.catcom.2013.06.019 WOS Scopus РИНЦ РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 22 мар. 2013 г. |
| Принята к публикации: | 11 июн. 2013 г. |
| Опубликована online: | 23 июн. 2013 г. |
| Опубликована в печати: | 5 окт. 2013 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000323016400024 |
| ≡ Scopus: | 2-s2.0-84978023653 |
| ≡ РИНЦ: | 20439113 | 41773561 |
| ≡ OpenAlex: | W2006568810 |
| ≡ Chemical Abstracts: | 2013:1142910 |
| ≡ Chemical Abstracts (print): | 159:275450 |