Cocatalytic Effect of Palladium and Zinc in the Condensation of Alcohol Carbon Backbones into Hydrocarbons | Sciact - CRIS-система Института катализа

Cocatalytic Effect of Palladium and Zinc in the Condensation of Alcohol Carbon Backbones into Hydrocarbons Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2011, Том: 52, Номер: 2, Страницы: 258-272 Страниц : 5 DOI: 10.1134/S0023158411020030

Ключевые слова

Palladium; Reaction Path; Aliphatic Hydrocarbon; Ethanol Conversion; PdZn

Авторы

Chistyakov A.V. ¹ , Tsodikov M.V. ¹ , Murzin V.Yu. ¹ , Yandieva F.A. ¹ , Zubavichus Yu.V. ² , Kozitsyna N.Y. ³ , Gekhman A.E. ³ , Kriventsov V.V. ⁴ , Moiseev I.I. ¹

Организации

1	Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia
2	Kurchatov Institute Russian Research Center, Moscow, 123182, Russia
3	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia
4	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

The results of the direct conversion of ethanol and its mixture with glycerol into a C4–C10+ alkane and olefin fraction in the presence of Pd-, Zn-, and Pd-Zn-containing catalysts, which were prepared by supporting homo- and heterometallic acetate complexes onto the surface of γ-Al2O3, are reported. It was found that, in the presence of mono- and bicomponent Pd-ZnO (Pd; ZnO)/γ-Al2O3 systems, selectivity in the formation of alkanes, olefins, or their mixtures in the target fraction can be controlled as a result of the cocatalytic effect of active components that are responsible for the catalyst activity in condensation and hydrogenation reactions. The structures of the active components were studied and the genesis of the catalytic systems was characterized using XAFS, XPS, and XRD analysis. It was found that the addition of glycerol considerably increased the yield of the target hydrocarbon fraction.

Chistyakov A.V. , Tsodikov M.V. , Murzin V.Y. , Yandieva F.A. , Zubavichus Y.V. , Kozitsyna N.Y. , Gekhman A.E. , Kriventsov V.V. , Moiseev I.I.
Cocatalytic Effect of Palladium and Zinc in the Condensation of Alcohol Carbon Backbones into Hydrocarbons
Kinetics and Catalysis. 2011. V.52. N2. P.258-272. DOI: 10.1134/S0023158411020030 WOS Scopus РИНЦ CAPlusCA OpenAlex

Чистяков А.В. , Цодиков М.В. , Мурзин В.Ю. , Яндиева Ф.А. , Зубавичус Я.В. , Козицына Н.Ю. , Гехман А.Е. , Кривенцов В.В. , Моисеев И.И.
Сокаталитический эффект палладия и цинка в реакции конденсации углеродного остова спиртов в углеводороды
Кинетика и катализ. 2011. Т.52. №2. С.266-281. РИНЦ

Поступила в редакцию:	2 июл. 2010 г.
Опубликована в печати:	1 мар. 2011 г.
Опубликована online:	7 апр. 2011 г.

Web of science:	WOS:000289254900016
Scopus:	2-s2.0-79953845617
РИНЦ:	16991671
Chemical Abstracts:	2011:438065
Chemical Abstracts (print):	154:567160
OpenAlex:	W1989901305

БД	Цитирований
Web of science	21
Scopus	18
РИНЦ	18
OpenAlex	23