Cocatalytic Effect of Palladium and Zinc in the Condensation of Alcohol Carbon Backbones into Hydrocarbons | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cocatalytic Effect of Palladium and Zinc in the Condensation of Alcohol Carbon Backbones into Hydrocarbons Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 2011, Volume: 52, Number: 2, Pages: 258-272 Pages count : 5 DOI: 10.1134/S0023158411020030

Tags

Palladium; Reaction Path; Aliphatic Hydrocarbon; Ethanol Conversion; PdZn

Authors

Chistyakov A.V. ¹ , Tsodikov M.V. ¹ , Murzin V.Yu. ¹ , Yandieva F.A. ¹ , Zubavichus Yu.V. ² , Kozitsyna N.Y. ³ , Gekhman A.E. ³ , Kriventsov V.V. ⁴ , Moiseev I.I. ¹

Affiliations

1	Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia
2	Kurchatov Institute Russian Research Center, Moscow, 123182, Russia
3	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia
4	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

The results of the direct conversion of ethanol and its mixture with glycerol into a C4–C10+ alkane and olefin fraction in the presence of Pd-, Zn-, and Pd-Zn-containing catalysts, which were prepared by supporting homo- and heterometallic acetate complexes onto the surface of γ-Al2O3, are reported. It was found that, in the presence of mono- and bicomponent Pd-ZnO (Pd; ZnO)/γ-Al2O3 systems, selectivity in the formation of alkanes, olefins, or their mixtures in the target fraction can be controlled as a result of the cocatalytic effect of active components that are responsible for the catalyst activity in condensation and hydrogenation reactions. The structures of the active components were studied and the genesis of the catalytic systems was characterized using XAFS, XPS, and XRD analysis. It was found that the addition of glycerol considerably increased the yield of the target hydrocarbon fraction.

Chistyakov A.V. , Tsodikov M.V. , Murzin V.Y. , Yandieva F.A. , Zubavichus Y.V. , Kozitsyna N.Y. , Gekhman A.E. , Kriventsov V.V. , Moiseev I.I.
Cocatalytic Effect of Palladium and Zinc in the Condensation of Alcohol Carbon Backbones into Hydrocarbons
Kinetics and Catalysis. 2011. V.52. N2. P.258-272. DOI: 10.1134/S0023158411020030 WOS Scopus РИНЦ ANCAN OpenAlex

Чистяков А.В. , Цодиков М.В. , Мурзин В.Ю. , Яндиева Ф.А. , Зубавичус Я.В. , Козицына Н.Ю. , Гехман А.Е. , Кривенцов В.В. , Моисеев И.И.
Сокаталитический эффект палладия и цинка в реакции конденсации углеродного остова спиртов в углеводороды
Кинетика и катализ. 2011. Т.52. №2. С.266-281. РИНЦ

Submitted:	Jul 2, 2010
Published print:	Mar 1, 2011
Published online:	Apr 7, 2011

Web of science:	WOS:000289254900016
Scopus:	2-s2.0-79953845617
Elibrary:	16991671
Chemical Abstracts:	2011:438065
Chemical Abstracts (print):	154:567160
OpenAlex:	W1989901305

DB	Citing
Web of science	21
Scopus	18
Elibrary	18
OpenAlex	23