One-Step Solvent-Free Synthesis of Cyclic Carbonates by Oxidativecarboxylation of Styrenes over a Recyclable Ti-Containing Catalyst | Sciact - CRIS-система Института катализа

One-Step Solvent-Free Synthesis of Cyclic Carbonates by Oxidativecarboxylation of Styrenes over a Recyclable Ti-Containing Catalyst Научная публикация

Журнал

Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883

Вых. Данные

Год: 2016, Том: 181, Страницы: 363-370 Страниц : 8 DOI: 10.1016/j.apcatb.2015.08.010

Ключевые слова

Carbon dioxide, Cyclic carbonate, Mesoporous titanium-silicate, Oxidative carboxylation, Styrene

Авторы

Maksimchuk Nataliya V. ^1,2 , Ivanchikova Irina D. ^1,3 , Ayupov Artem B. ¹ , Kholdeeva Oxana A. ^1,2

Организации

1	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova str. 2, Novosibirsk 630090, Russia
3	Tomsk State University, Pr. Lenina 36, Tomsk 634050, Russia

Информация о финансировании (3)

1	Российский фонд фундаментальных исследований	15-33-20225
2	Российский фонд фундаментальных исследований	13-03-00413
3	Министерство образования и науки Российской Федерации

A mesoporous titanium-silicate prepared by evaporation-induced self-assembly is an efficient hetero-geneous catalyst for the one-step oxidative carboxylation of styrenes with tert-butyl hydroperoxide andcarbon dioxide in the presence of tetrabutylammonium bromide as cocatalyst under mild solvent-freeconditions (50–70◦C, 8 bar CO2). The selectivity to cyclic carbonates reaches 69–70% at 92–98.5% sub-strate conversion. The catalyst can be easily recovered by filtration and reused several times without asignificant deterioration of the catalytic performance. The volume yield of SC as high as 1.1 kg/L could beachieved after seven reuses.

Maksimchuk N.V. , Ivanchikova I.D. , Ayupov A.B. , Kholdeeva O.A.
One-Step Solvent-Free Synthesis of Cyclic Carbonates by Oxidativecarboxylation of Styrenes over a Recyclable Ti-Containing Catalyst
Applied Catalysis B: Environmental. 2016. V.181. P.363-370. DOI: 10.1016/j.apcatb.2015.08.010 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	27 мар. 2015 г.
Принята к публикации:	4 авг. 2015 г.
Опубликована online:	8 авг. 2015 г.
Опубликована в печати:	1 февр. 2016 г.

Web of science:	WOS:000364256000033
Scopus:	2-s2.0-84939864686
РИНЦ:	24934002
Chemical Abstracts:	2015:1396349
Chemical Abstracts (print):	163:374220
OpenAlex:	W1451751334

БД	Цитирований
Web of science	49
Scopus	52
РИНЦ	47
OpenAlex	51