One-Step Solvent-Free Synthesis of Cyclic Carbonates by Oxidativecarboxylation of Styrenes over a Recyclable Ti-Containing Catalyst Full article
| Journal |
Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883 |
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| Output data | Year: 2016, Volume: 181, Pages: 363-370 Pages count : 8 DOI: 10.1016/j.apcatb.2015.08.010 | ||||||
| Tags | Carbon dioxide, Cyclic carbonate, Mesoporous titanium-silicate, Oxidative carboxylation, Styrene | ||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 13-03-00413 |
| 2 | Russian Foundation for Basic Research | 15-33-20225 |
| 3 | The Ministry of Education and Science of the Russian Federation |
Abstract:
A mesoporous titanium-silicate prepared by evaporation-induced self-assembly is an efficient hetero-geneous catalyst for the one-step oxidative carboxylation of styrenes with tert-butyl hydroperoxide andcarbon dioxide in the presence of tetrabutylammonium bromide as cocatalyst under mild solvent-freeconditions (50–70◦C, 8 bar CO2). The selectivity to cyclic carbonates reaches 69–70% at 92–98.5% sub-strate conversion. The catalyst can be easily recovered by filtration and reused several times without asignificant deterioration of the catalytic performance. The volume yield of SC as high as 1.1 kg/L could beachieved after seven reuses.
Cite:
Maksimchuk N.V.
, Ivanchikova I.D.
, Ayupov A.B.
, Kholdeeva O.A.
One-Step Solvent-Free Synthesis of Cyclic Carbonates by Oxidativecarboxylation of Styrenes over a Recyclable Ti-Containing Catalyst
Applied Catalysis B: Environmental. 2016. V.181. P.363-370. DOI: 10.1016/j.apcatb.2015.08.010 WOS Scopus РИНЦ OpenAlex ANCAN
One-Step Solvent-Free Synthesis of Cyclic Carbonates by Oxidativecarboxylation of Styrenes over a Recyclable Ti-Containing Catalyst
Applied Catalysis B: Environmental. 2016. V.181. P.363-370. DOI: 10.1016/j.apcatb.2015.08.010 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Mar 27, 2015 |
| Accepted: | Aug 4, 2015 |
| Published online: | Aug 8, 2015 |
| Published print: | Feb 1, 2016 |
Identifiers:
| ≡ Web of science: | WOS:000364256000033 |
| ≡ Scopus: | 2-s2.0-84939864686 |
| ≡ Elibrary: | 24934002 |
| ≡ OpenAlex: | W1451751334 |
| ≡ Chemical Abstracts: | 2015:1396349 |
| ≡ Chemical Abstracts (print): | 163:374220 |