Design of Highly Efficient Catalyst for Rational Way of Direct Conversion of Methane | Sciact - CRIS-система Института катализа

Design of Highly Efficient Catalyst for Rational Way of Direct Conversion of Methane Научная публикация

Журнал

Eurasian Chemico-Technological Journal
ISSN: 1562-3920

Вых. Данные

Год: 2015, Том: 17, Номер: 2, Страницы: 105-118 Страниц : 4 DOI: 10.18321/ectj201

Ключевые слова

CATALYST, METHANE

Авторы

Ismagilov I.Z. ¹ , Matus E.V. ¹ , Kerzhentsev M.A. ¹ , Prosvirin I.P. ¹ , Navarro R.M. ² , Fierro J.L.G. ² , Gerritsen G. ³ , Abbenhuis E. ³ , Ismagilov Z.R. ^1,4

Организации

1	Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
2	Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie 2, 28049 Madrid, Spain
3	Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
4	Institute of Coal Chemistry and Material Science SB RAS, pr. Sovetskiy 18, 650000 Kemerovo, Russia

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	V.45.1.10.
2	European Commission	262840 FP7-NMP-2010-LARGE-4 DEMCAMER

Effects of composition and preparation method of MnNaW/SiO2 and LaSr/CaO catalysts on their physical-chemical properties and performance in oxidative coupling of methane (OCM) have been studied. For MnNaW/SiO2 catalysts the synthesis method and type of SiO2 have a significant effect on the texture, while the Na/W ratio determines the phase composition. The variation of preparation method and temperature of catalyst calcination allows regulation of the metal surface concentration and mode of metal distribution across the SiO2 support. For LaSr/CaO catalysts the synthesis method determines the specific surface area, surface and phase composition. Correlations between catalyst performance, preparation method and state of the catalyst were established. The rational preparation procedure and perspective composition of OCM catalyst have been developed. The 20La/CaO catalysts prepared by citrate sol-gel method were shown to provide ~20% C2 yield and ~40% methane conversion at 800 °C.

Ismagilov I.Z. , Matus E.V. , Kerzhentsev M.A. , Prosvirin I.P. , Navarro R.M. , Fierro J.L.G. , Gerritsen G. , Abbenhuis E. , Ismagilov Z.R.
Design of Highly Efficient Catalyst for Rational Way of Direct Conversion of Methane

Eurasian Chemico-Technological Journal. 2015. V.17. N2. P.105-118. DOI: 10.18321/ectj201 WOS Scopus РИНЦ CAPlus OpenAlex

Полный текст от издателя

Поступила в редакцию:	21 окт. 2014 г.
Опубликована в печати:	1 янв. 2015 г.
Принята к публикации:	18 февр. 2015 г.
Опубликована online:	11 мар. 2015 г.

Web of science:	WOS:000420247000004
Scopus:	2-s2.0-84964938479
РИНЦ:	26445700
Chemical Abstracts:	2018:617737
OpenAlex:	W2248345781

БД	Цитирований
Web of science	9
Scopus	8
РИНЦ	14
OpenAlex	7