Design of Highly Efficient Catalyst for Rational Way of Direct Conversion of Methane | Sciact - CRIS-system of Boreskov Institute of Catalysis

Design of Highly Efficient Catalyst for Rational Way of Direct Conversion of Methane Full article

Journal

Eurasian Chemico-Technological Journal
ISSN: 1562-3920

Output data

Year: 2015, Volume: 17, Number: 2, Pages: 105-118 Pages count : 4 DOI: 10.18321/ectj201

Tags

CATALYST, METHANE

Authors

Ismagilov I.Z. ¹ , Matus E.V. ¹ , Kerzhentsev M.A. ¹ , Prosvirin I.P. ¹ , Navarro R.M. ² , Fierro J.L.G. ² , Gerritsen G. ³ , Abbenhuis E. ³ , Ismagilov Z.R. ^1,4

Affiliations

1	Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
2	Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie 2, 28049 Madrid, Spain
3	Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
4	Institute of Coal Chemistry and Material Science SB RAS, pr. Sovetskiy 18, 650000 Kemerovo, Russia

Funding (2)

1	Federal Agency for Scientific Organizations	V.45.1.10.
2	European Commission	262840 FP7-NMP-2010-LARGE-4 DEMCAMER

Effects of composition and preparation method of MnNaW/SiO2 and LaSr/CaO catalysts on their physical-chemical properties and performance in oxidative coupling of methane (OCM) have been studied. For MnNaW/SiO2 catalysts the synthesis method and type of SiO2 have a significant effect on the texture, while the Na/W ratio determines the phase composition. The variation of preparation method and temperature of catalyst calcination allows regulation of the metal surface concentration and mode of metal distribution across the SiO2 support. For LaSr/CaO catalysts the synthesis method determines the specific surface area, surface and phase composition. Correlations between catalyst performance, preparation method and state of the catalyst were established. The rational preparation procedure and perspective composition of OCM catalyst have been developed. The 20La/CaO catalysts prepared by citrate sol-gel method were shown to provide ~20% C2 yield and ~40% methane conversion at 800 °C.

Ismagilov I.Z. , Matus E.V. , Kerzhentsev M.A. , Prosvirin I.P. , Navarro R.M. , Fierro J.L.G. , Gerritsen G. , Abbenhuis E. , Ismagilov Z.R.
Design of Highly Efficient Catalyst for Rational Way of Direct Conversion of Methane

Eurasian Chemico-Technological Journal. 2015. V.17. N2. P.105-118. DOI: 10.18321/ectj201 WOS Scopus РИНЦ AN OpenAlex

Full text from publisher

Submitted:	Oct 21, 2014
Published print:	Jan 1, 2015
Accepted:	Feb 18, 2015
Published online:	Mar 11, 2015

Web of science:	WOS:000420247000004
Scopus:	2-s2.0-84964938479
Elibrary:	26445700
Chemical Abstracts:	2018:617737
OpenAlex:	W2248345781

DB	Citing
Web of science	9
Scopus	8
Elibrary	14
OpenAlex	7