Study on Thermal Decomposition of Double Complex Salt [Pd (NH3) 4][PtCl6] | Sciact - CRIS-система Института катализа

Study on Thermal Decomposition of Double Complex Salt [Pd (NH3) 4][PtCl6] Научная публикация

Журнал

Journal of Thermal Analysis and Calorimetry
ISSN: 1388-6150 , E-ISSN: 1572-8943

Вых. Данные

Год: 2016, Том: 123, Номер: 2, Страницы: 1183-1195 Страниц : 13 DOI: 10.1007/s10973-015-5002-5

Ключевые слова

PdPt alloy nanoparticles, Thermal analysis, Thermal decomposition, XPS, XRD, [Pd(NH3)4][PtCl6]

Авторы

Asanova Tatyana ¹ , Asanov Igor ^1,2 , Zadesenets Andrey ^1,2 , Filatov Evgeniy ^1,2 , Plyusnin Pavel ^1,2 , Gerasimov Evgeniy ³ , Korenev Sergey ^1,2

Организации

1	Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia 630090
2	Novosibirsk State University, Novosibirsk, Russia 630090
3	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia 630090

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	12-02-00354
2	Российский фонд фундаментальных исследований	14-03-00129

Thermal decomposition of double complex salt [Pd(NH3)4][PtCl6] in a helium atmosphere has been studied by ex situ X-ray diffraction, X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy. Statistical multivariate curve resolution approach to XPS and Auger spectra analysis was applied. This approach was compared with a convenient XPS analysis, demonstrating comparable results and its effectiveness in analysis of sample containing components with various oxidation states, but a little difference in composition. The result obtained allows the complex salt to use as a perspective single-source precursor in one-pot synthesis of PdPt alloy nanoparticles. To examine the precursor, thermal decomposition and shock of [Pd(NH3)4][PtCl6] were performed under various conditions in inert and reduction atmospheres and the final products were studied

Asanova T. , Asanov I. , Zadesenets A. , Filatov E. , Plyusnin P. , Gerasimov E. , Korenev S.
Study on Thermal Decomposition of Double Complex Salt [Pd (NH3) 4][PtCl6]
Journal of Thermal Analysis and Calorimetry. 2016. V.123. N2. P.1183-1195. DOI: 10.1007/s10973-015-5002-5 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	1 июн. 2015 г.
Принята к публикации:	19 авг. 2015 г.
Опубликована online:	29 сент. 2015 г.
Опубликована в печати:	1 февр. 2016 г.

Web of science:	WOS:000368199500031
Scopus:	2-s2.0-84954286920
РИНЦ:	27029759
Chemical Abstracts:	2015:1589251
Chemical Abstracts (print):	164:242970
OpenAlex:	W2483897207

БД	Цитирований
Web of science	15
Scopus	15
РИНЦ	16
OpenAlex	16