Study on Thermal Decomposition of Double Complex Salt [Pd (NH3) 4][PtCl6] Full article
| Journal |
Journal of Thermal Analysis and Calorimetry
ISSN: 1388-6150 , E-ISSN: 1572-8943 |
||||||
|---|---|---|---|---|---|---|---|
| Output data | Year: 2016, Volume: 123, Number: 2, Pages: 1183-1195 Pages count : 13 DOI: 10.1007/s10973-015-5002-5 | ||||||
| Tags | PdPt alloy nanoparticles, Thermal analysis, Thermal decomposition, XPS, XRD, [Pd(NH3)4][PtCl6] | ||||||
| Authors |
|
||||||
| Affiliations |
|
Funding (2)
| 1 | Russian Foundation for Basic Research | 12-02-00354 |
| 2 | Russian Foundation for Basic Research | 14-03-00129 |
Abstract:
Thermal decomposition of double complex salt [Pd(NH3)4][PtCl6] in a helium atmosphere has been studied by ex situ X-ray diffraction, X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy. Statistical multivariate curve resolution approach to XPS and Auger spectra analysis was applied. This approach was compared with a convenient XPS analysis, demonstrating comparable results and its effectiveness in analysis of sample containing components with various oxidation states, but a little difference in composition. The result obtained allows the complex salt to use as a perspective single-source precursor in one-pot synthesis of PdPt alloy nanoparticles. To examine the precursor, thermal decomposition and shock of [Pd(NH3)4][PtCl6] were performed under various conditions in inert and reduction atmospheres and the final products were studied
Cite:
Asanova T.
, Asanov I.
, Zadesenets A.
, Filatov E.
, Plyusnin P.
, Gerasimov E.
, Korenev S.
Study on Thermal Decomposition of Double Complex Salt [Pd (NH3) 4][PtCl6]
Journal of Thermal Analysis and Calorimetry. 2016. V.123. N2. P.1183-1195. DOI: 10.1007/s10973-015-5002-5 WOS Scopus РИНЦ ANCAN OpenAlex
Study on Thermal Decomposition of Double Complex Salt [Pd (NH3) 4][PtCl6]
Journal of Thermal Analysis and Calorimetry. 2016. V.123. N2. P.1183-1195. DOI: 10.1007/s10973-015-5002-5 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jun 1, 2015 |
| Accepted: | Aug 19, 2015 |
| Published online: | Sep 29, 2015 |
| Published print: | Feb 1, 2016 |
Identifiers:
| Web of science: | WOS:000368199500031 |
| Scopus: | 2-s2.0-84954286920 |
| Elibrary: | 27029759 |
| Chemical Abstracts: | 2015:1589251 |
| Chemical Abstracts (print): | 164:242970 |
| OpenAlex: | W2483897207 |