Reactions of Polyfluorobenzenethiols with Polyhalomethanes and Their Derivatives in an Alkaline Medium | Sciact - CRIS-система Института катализа

Reactions of Polyfluorobenzenethiols with Polyhalomethanes and Their Derivatives in an Alkaline Medium Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Вых. Данные

Год: 2015, Том: 51, Номер: 11, Страницы: 1551-1559 Страниц : 9 DOI: 10.1134/S1070428015110068

Ключевые слова

Thiol; Steam Distillation; Sulfanyl; Benzenethiol; Tetrafluorophenyl

Авторы

Bredikhin R.A. ^1,2 , Maksimov A.M. ¹ , Gatilov Y.V. ^1,2 , Kireenkov V.V. ³ , Platonov V.E. ¹

Организации

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Academika Lavrent’eva 9, Novosibirsk, 630090 Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

New process direction was found in the reaction of polyfluoroarenethiols with fluorodichloromethane, chloroform, and bromoform in an alkaline medium consisting in the replacement of the thiol group by a hydrogen atom. This process competes with the formation of expected products, dihalomethyl polyfluoro-aryl sulfides and tris(arylsulfanyl)methanes. In reaction of 2,3,5,6-tetrafluorobenzenethiol with dichloro-methane bis(2,3,5,6-tetrafluorophenylsulfanyl)methane was obtained. Reactions of polyfluoroarenethiols with pentafluorobenzyl chloride occur mainly with the substitution of the chlorine atom, with pentafluorobenzal chloride and with pentafluorobenzotrichloride a substitution of a fluorine atom in the para-position takes place

Bredikhin R.A. , Maksimov A.M. , Gatilov Y.V. , Kireenkov V.V. , Platonov V.E.
Reactions of Polyfluorobenzenethiols with Polyhalomethanes and Their Derivatives in an Alkaline Medium
Russian Journal of Organic Chemistry. 2015. V.51. N11. P.1551-1559. DOI: 10.1134/S1070428015110068 WOS Scopus РИНЦ CAPlusCA OpenAlex

Бредихин Р.А. , Максимов А.М. , Гатилов Ю.В. , Киреенков В.В. , Платонов В.Е.
Реакции полифторбензолтиолов с полигалогенметанами и их производными в щелочной среде
Журнал органической химии. 2015. Т.51. №11. С.1582-1590. РИНЦ

Поступила в редакцию:	29 июн. 2015 г.
Опубликована в печати:	1 нояб. 2015 г.
Опубликована online:	24 дек. 2015 г.

Web of science:	WOS:000367346500006
Scopus:	2-s2.0-84951287023
РИНЦ:	26806933
Chemical Abstracts:	2015:2070612
Chemical Abstracts (print):	164:148747
OpenAlex:	W2251590209

БД	Цитирований
Web of science	3
Scopus	3
OpenAlex	7