Reactions of Polyfluorobenzenethiols with Polyhalomethanes and Their Derivatives in an Alkaline Medium | Sciact - CRIS-system of Boreskov Institute of Catalysis

Reactions of Polyfluorobenzenethiols with Polyhalomethanes and Their Derivatives in an Alkaline Medium Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2015, Volume: 51, Number: 11, Pages: 1551-1559 Pages count : 9 DOI: 10.1134/S1070428015110068

Tags

Thiol; Steam Distillation; Sulfanyl; Benzenethiol; Tetrafluorophenyl

Authors

Bredikhin R.A. ^1,2 , Maksimov A.M. ¹ , Gatilov Y.V. ^1,2 , Kireenkov V.V. ³ , Platonov V.E. ¹

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Academika Lavrent’eva 9, Novosibirsk, 630090 Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

New process direction was found in the reaction of polyfluoroarenethiols with fluorodichloromethane, chloroform, and bromoform in an alkaline medium consisting in the replacement of the thiol group by a hydrogen atom. This process competes with the formation of expected products, dihalomethyl polyfluoro-aryl sulfides and tris(arylsulfanyl)methanes. In reaction of 2,3,5,6-tetrafluorobenzenethiol with dichloro-methane bis(2,3,5,6-tetrafluorophenylsulfanyl)methane was obtained. Reactions of polyfluoroarenethiols with pentafluorobenzyl chloride occur mainly with the substitution of the chlorine atom, with pentafluorobenzal chloride and with pentafluorobenzotrichloride a substitution of a fluorine atom in the para-position takes place

Bredikhin R.A. , Maksimov A.M. , Gatilov Y.V. , Kireenkov V.V. , Platonov V.E.
Reactions of Polyfluorobenzenethiols with Polyhalomethanes and Their Derivatives in an Alkaline Medium
Russian Journal of Organic Chemistry. 2015. V.51. N11. P.1551-1559. DOI: 10.1134/S1070428015110068 WOS Scopus РИНЦ ANCAN OpenAlex

Бредихин Р.А. , Максимов А.М. , Гатилов Ю.В. , Киреенков В.В. , Платонов В.Е.
Реакции полифторбензолтиолов с полигалогенметанами и их производными в щелочной среде
Журнал органической химии. 2015. Т.51. №11. С.1582-1590. РИНЦ

Submitted:	Jun 29, 2015
Published print:	Nov 1, 2015
Published online:	Dec 24, 2015

Web of science:	WOS:000367346500006
Scopus:	2-s2.0-84951287023
Elibrary:	26806933
Chemical Abstracts:	2015:2070612
Chemical Abstracts (print):	164:148747
OpenAlex:	W2251590209

DB	Citing
Web of science	3
Scopus	3
OpenAlex	7