Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism | Sciact - CRIS-система Института катализа

Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism Обзор

Конференция

11th European Workshop on Selective Oxidation - Selectivity in Oxidation - Key to New Resources Valorization (ISO) during the 12th European Congress on Catalysis - Balancing the Use of Fossil and Renewable Resources (Europacat)
30 авг. - 4 сент. 2015 , Kazan

Журнал

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Вых. Данные

Год: 2016, Том: 278, Номер: Part 1, Страницы: 30-39 Страниц : 10 DOI: 10.1016/j.cattod.2016.04.033

Ключевые слова

Asymmetric catalysis, Enantioselective, Epoxidation, Hydrogen peroxide, Manganese, Mechanism

Авторы

Ottenbacher Roman V. ^1,2 , Talsi Evgenii P. ^1,2 , Bryliakov Konstantin P. ^1,2

Организации

1	Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russia
2	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russia

Информация о финансировании (1)

Российский научный фонд

14-13-00158

This mini-review summarizes the progress in the asymmetric epoxidation of olefins in the presence of manganese aminopyridine complexes, achieved in the last decade. The major breakthroughs in catalyst design, that eventually led to the emergence of highly enantioselective (> 99% ee) and efficient (> 1000 TON) catalysts, are discussed. The mechanistic studies carried out in recent years are given particular attention.

Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism
Catalysis Today. 2016. V.278. NPart 1. P.30-39. DOI: 10.1016/j.cattod.2016.04.033 WOS Scopus РИНЦ OpenAlex CAPlusCA

Поступила в редакцию:	17 нояб. 2015 г.
Принята к публикации:	25 апр. 2016 г.
Опубликована online:	12 мая 2016 г.
Опубликована в печати:	1 дек. 2016 г.

≡ Web of science:	WOS:000388053000004
≡ Scopus:	2-s2.0-84992736484
≡ РИНЦ:	28170041
≡ OpenAlex:	W2364384387
≡ Chemical Abstracts:	2016:748637
≡ Chemical Abstracts (print):	165:499763

≡ Web of science	25	Сбор данных от 20.02.2026
≡ Scopus	23	Сбор данных от 22.02.2026
≡ РИНЦ	25	Сбор данных от 22.02.2026
≡ OpenAlex	28	Сбор данных от 22.02.2026