Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism Review
| Conference |
11th European Workshop on Selective Oxidation - Selectivity in Oxidation - Key to New Resources Valorization (ISO) during the 12th European Congress on Catalysis - Balancing the Use of Fossil and Renewable Resources (Europacat) 30 Aug - 4 Sep 2015 , Kazan |
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| Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Output data | Year: 2016, Volume: 278, Number: Part 1, Pages: 30-39 Pages count : 10 DOI: 10.1016/j.cattod.2016.04.033 | ||||
| Tags | Asymmetric catalysis, Enantioselective, Epoxidation, Hydrogen peroxide, Manganese, Mechanism | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-13-00158 |
Abstract:
This mini-review summarizes the progress in the asymmetric epoxidation of olefins in the presence of manganese aminopyridine complexes, achieved in the last decade. The major breakthroughs in catalyst design, that eventually led to the emergence of highly enantioselective (> 99% ee) and efficient (> 1000 TON) catalysts, are discussed. The mechanistic studies carried out in recent years are given particular attention.
Cite:
Ottenbacher R.V.
, Talsi E.P.
, Bryliakov K.P.
Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism
Catalysis Today. 2016. V.278. NPart 1. P.30-39. DOI: 10.1016/j.cattod.2016.04.033 WOS Scopus РИНЦ OpenAlex ANCAN
Bioinspired Mn-Aminopyridine Catalyzed Epoxidations of Olefins with Various Oxidants: Enantioselectivity and Mechanism
Catalysis Today. 2016. V.278. NPart 1. P.30-39. DOI: 10.1016/j.cattod.2016.04.033 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Nov 17, 2015 |
| Accepted: | Apr 25, 2016 |
| Published online: | May 12, 2016 |
| Published print: | Dec 1, 2016 |
Identifiers:
| ≡ Web of science: | WOS:000388053000004 |
| ≡ Scopus: | 2-s2.0-84992736484 |
| ≡ Elibrary: | 28170041 |
| ≡ OpenAlex: | W2364384387 |
| ≡ Chemical Abstracts: | 2016:748637 |
| ≡ Chemical Abstracts (print): | 165:499763 |