Electronic and Chemical Properties of Nanostructured Cerium Dioxide Doped with Praseodymium | Sciact - CRIS-система Института катализа

Electronic and Chemical Properties of Nanostructured Cerium Dioxide Doped with Praseodymium Научная публикация

Журнал

The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207

Вых. Данные

Год: 2005, Том: 109, Номер: 12, Страницы: 5728-5738 Страниц : 11 DOI: 10.1021/jp045828c

Ключевые слова

Doping (additives); Fourier transform infrared spectroscopy; Ionic conduction; Nanostructured materials; Praseodymium; Reaction kinetics; Secondary ion mass spectrometry; Surface treatment; Temperature programmed desorption; Transmission electron microscopy; X ray diffraction analysis; X ray photoelectron spectroscopy

Авторы

Borchert Holger ¹ , Frolova Yulia V. ^1,2 , Kaichev Vasiliy V. ¹ , Prosvirin Igor P. ¹ , Alikina Galina M. ¹ , Lukashevich Anton I. ¹ , Zaikovskii Vladimir I. ¹ , Moroz Ella M. ¹ , Trukhan Sergei N. ¹ , Ivanov Vyacheslav P. ¹ , Paukshtis Eugenii A. ¹ , Bukhtiyarov Valerii I. ¹ , Sadykov Vladislav A. ^1,2

Организации

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

Информация о финансировании (5)

1	International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union	01-2162
2	Международный научно-технический центр	2529
3	Президиум РАН	39
4	Министерство образования и науки Российской Федерации	3N-292-03
5	German Academic Exchange Service

Nanostructured doped ceria is a prospective material for catalytic applications such as the construction of membranes with mixed electronic and ionic conductivity for effective syngas production. In this article, the surface properties of nanostructured ceria doped with praseodymium have been studied by X-ray photoelectron spectroscopy, secondary ion mass spectrometry, and Fourier transform infrared spectroscopy of adsorbed carbon monoxide. The effects of supporting 1.4 wt % Pt as well as structural changes upon the reduction of the samples with methane have been investigated. While in samples without supported platinum, mainly praseodymium cations are reduced in a methane atmosphere; stronger reduction of cerium cations was found in the case of surface modification with Pt. The structural differences correlate with results from temperature-programmed reaction experiments with methane. Explanations are discussed in terms of different reaction mechanisms.

Borchert H. , Frolova Y.V. , Kaichev V.V. , Prosvirin I.P. , Alikina G.M. , Lukashevich A.I. , Zaikovskii V.I. , Moroz E.M. , Trukhan S.N. , Ivanov V.P. , Paukshtis E.A. , Bukhtiyarov V.I. , Sadykov V.A.
Electronic and Chemical Properties of Nanostructured Cerium Dioxide Doped with Praseodymium
The Journal of Physical Chemistry B. 2005. V.109. N12. P.5728-5738. DOI: 10.1021/jp045828c WOS Scopus РИНЦ CAPlusCA PMID OpenAlex

Поступила в редакцию:	15 сент. 2004 г.
Принята к публикации:	26 нояб. 2004 г.
Опубликована в печати:	1 мар. 2005 г.
Опубликована online:	4 мар. 2005 г.

Web of science:	WOS:000227993800056
Scopus:	2-s2.0-20244376173
РИНЦ:	13500564
Chemical Abstracts:	2005:180184
Chemical Abstracts (print):	142:417777
PMID (PubMed):	16851621
OpenAlex:	W2014907170

БД	Цитирований
Web of science	181
Scopus	189
РИНЦ	184
OpenAlex	188