Electronic and Chemical Properties of Nanostructured Cerium Dioxide Doped with Praseodymium | Sciact - CRIS-system of Boreskov Institute of Catalysis

Electronic and Chemical Properties of Nanostructured Cerium Dioxide Doped with Praseodymium Full article

Journal

The Journal of Physical Chemistry B
ISSN: 1520-6106 , E-ISSN: 1520-5207

Output data

Year: 2005, Volume: 109, Number: 12, Pages: 5728-5738 Pages count : 11 DOI: 10.1021/jp045828c

Tags

Doping (additives); Fourier transform infrared spectroscopy; Ionic conduction; Nanostructured materials; Praseodymium; Reaction kinetics; Secondary ion mass spectrometry; Surface treatment; Temperature programmed desorption; Transmission electron microscopy; X ray diffraction analysis; X ray photoelectron spectroscopy

Authors

Borchert Holger ¹ , Frolova Yulia V. ^1,2 , Kaichev Vasiliy V. ¹ , Prosvirin Igor P. ¹ , Alikina Galina M. ¹ , Lukashevich Anton I. ¹ , Zaikovskii Vladimir I. ¹ , Moroz Ella M. ¹ , Trukhan Sergei N. ¹ , Ivanov Vyacheslav P. ¹ , Paukshtis Eugenii A. ¹ , Bukhtiyarov Valerii I. ¹ , Sadykov Vladislav A. ^1,2

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia

Funding (5)

1	International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union	01-2162
2	International Science and Technology Center	2529
3	Президиум РАН	39
4	The Ministry of Education and Science of the Russian Federation	3N-292-03
5	German Academic Exchange Service

Nanostructured doped ceria is a prospective material for catalytic applications such as the construction of membranes with mixed electronic and ionic conductivity for effective syngas production. In this article, the surface properties of nanostructured ceria doped with praseodymium have been studied by X-ray photoelectron spectroscopy, secondary ion mass spectrometry, and Fourier transform infrared spectroscopy of adsorbed carbon monoxide. The effects of supporting 1.4 wt % Pt as well as structural changes upon the reduction of the samples with methane have been investigated. While in samples without supported platinum, mainly praseodymium cations are reduced in a methane atmosphere; stronger reduction of cerium cations was found in the case of surface modification with Pt. The structural differences correlate with results from temperature-programmed reaction experiments with methane. Explanations are discussed in terms of different reaction mechanisms.

Borchert H. , Frolova Y.V. , Kaichev V.V. , Prosvirin I.P. , Alikina G.M. , Lukashevich A.I. , Zaikovskii V.I. , Moroz E.M. , Trukhan S.N. , Ivanov V.P. , Paukshtis E.A. , Bukhtiyarov V.I. , Sadykov V.A.
Electronic and Chemical Properties of Nanostructured Cerium Dioxide Doped with Praseodymium
The Journal of Physical Chemistry B. 2005. V.109. N12. P.5728-5738. DOI: 10.1021/jp045828c WOS Scopus РИНЦ ANCAN PMID OpenAlex

Submitted:	Sep 15, 2004
Accepted:	Nov 26, 2004
Published print:	Mar 1, 2005
Published online:	Mar 4, 2005

Web of science:	WOS:000227993800056
Scopus:	2-s2.0-20244376173
Elibrary:	13500564
Chemical Abstracts:	2005:180184
Chemical Abstracts (print):	142:417777
PMID:	16851621
OpenAlex:	W2014907170

DB	Citing
Web of science	182
Scopus	190
Elibrary	184
OpenAlex	190