Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen - Доклады на конференциях | Sciact - CRIS-система Института катализа

Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen Доклады на конференциях

Язык

Английский

Тип доклада

Стендовый

Конференция

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 авг. 2017 , Florence

Авторы

Kovtunov Kirill ¹ , Salnikov Oleg ¹ , Burueva Dudari ¹ , Romanov Alexey ¹ , Bukhtiyarov Valerii ² , Fedorov Alexey ³ , Copéret Christophe ³ , Koptyug Igor ¹

Организации

1	Институт "Международный томографический центр" СО РАН
2	Институт катализа им. Г.К. Борескова СО РАН
3	Swiss Federal Institute of Technology in Zurich

Parahydrogen-induced polarization technique (PHIP) was successfully utilized for the mechanistic investigation of the hydrogen addition selectivity over different supported metal catalysts. New insights into the semihydrogenation of 1-butyne and 2-butyne on silica-supported Cu nanoparticles were obtained. Moreover, supported palladium catalysts were also investigated in the terms of catalyst active site structure influence on the pairwise hydrogen addition selectivity and was found that the differences in the mechanism of pairwise hydrogen addition to double and triple bonds over these palladium catalysts are existed.

Kovtunov K. , Salnikov O. , Burueva D. , Romanov A. , Bukhtiyarov V. , Fedorov A. , Copéret C. , Koptyug I.
Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen
EuropaCat-XIII: 13th European Congress on Catalysis 27-31 Aug 2017