Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen - Conference attendances | Sciact - CRIS-system of Boreskov Institute of Catalysis

Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen Conference attendances

Language

Английский

Participant type

Стендовый

Conference

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Authors

Kovtunov Kirill ¹ , Salnikov Oleg ¹ , Burueva Dudari ¹ , Romanov Alexey ¹ , Bukhtiyarov Valerii ² , Fedorov Alexey ³ , Copéret Christophe ³ , Koptyug Igor ¹

Affiliations

1	International Tomography Center SB RAS
2	Boreskov Institute of Catalysis SB RAS
3	Swiss Federal Institute of Technology in Zurich

Parahydrogen-induced polarization technique (PHIP) was successfully utilized for the mechanistic investigation of the hydrogen addition selectivity over different supported metal catalysts. New insights into the semihydrogenation of 1-butyne and 2-butyne on silica-supported Cu nanoparticles were obtained. Moreover, supported palladium catalysts were also investigated in the terms of catalyst active site structure influence on the pairwise hydrogen addition selectivity and was found that the differences in the mechanism of pairwise hydrogen addition to double and triple bonds over these palladium catalysts are existed.

Kovtunov K. , Salnikov O. , Burueva D. , Romanov A. , Bukhtiyarov V. , Fedorov A. , Copéret C. , Koptyug I.
Selective Heterogeneous Hydrogenation Investigations Using Parahydrogen
EuropaCat-XIII: 13th European Congress on Catalysis 27-31 Aug 2017