Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes Доклады на конференциях
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| Тип доклада | Устный | ||||
| Конференция |
27th International Chugaev Conference on Coordination Chemistry and 4th Young Conference School “Physicochemical Methods in the Chemistry of Coordination Compounds” 02-06 окт. 2017 , Нижний Новоород |
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Реферат:
In this work, a series of chiral iron(III) aminopyridine complexes have been prepared and
tested in the aerobic oxidative coupling of substituted β-naphthols. Upon 1 mol. % catalyst
loadings, these complexes ensure moderate to good yield of the corresponding BINOLs (up to
94 % within 24 h), having up to 55 % optical purity.
Библиографическая ссылка:
Tkachenko N.V.
, Lyakin O.Y.
, Talsi E.P.
, Bryliakov K.P.
Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes
27th International Chugaev Conference on Coordination Chemistry and 4th Young Conference School “Physicochemical Methods in the Chemistry of Coordination Compounds” 02-06 Oct 2017
Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes
27th International Chugaev Conference on Coordination Chemistry and 4th Young Conference School “Physicochemical Methods in the Chemistry of Coordination Compounds” 02-06 Oct 2017