Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes - Conference attendances | Sciact - CRIS-system of Boreskov Institute of Catalysis

Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes Conference attendances

Language

Английский

Participant type

Устный

Conference

27th International Chugaev Conference on Coordination Chemistry and 4th Young Conference School “Physicochemical Methods in the Chemistry of Coordination Compounds”
02-06 Oct 2017 , Нижний Новоород

Authors

Tkachenko Nikolay V. ^1,2 , Lyakin Oleg Yurʹevich ^1,2 , Talsi Evgeniy Pavlovich ^1,2 , Bryliakov Konstantin Petrovich ^1,2

Affiliations

1	Novosibirsk National Research University
2	Boreskov Institute of Catalysis SB RAS

In this work, a series of chiral iron(III) aminopyridine complexes have been prepared and tested in the aerobic oxidative coupling of substituted β-naphthols. Upon 1 mol. % catalyst loadings, these complexes ensure moderate to good yield of the corresponding BINOLs (up to 94 % within 24 h), having up to 55 % optical purity.

Tkachenko N.V. , Lyakin O.Y. , Talsi E.P. , Bryliakov K.P.
Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes
27th International Chugaev Conference on Coordination Chemistry and 4th Young Conference School “Physicochemical Methods in the Chemistry of Coordination Compounds” 02-06 Oct 2017