Process to prepare a solid support for a procatalyst for polymerization of olefins
Patents
Language: |
Английский |
Type: |
Invention |
Number |
US 20240010759 A1 |
Request number: |
18/038,610 |
Request date: |
Nov 25, 2021 |
patent.field.start_date: |
May 24, 2023 |
Registration date: |
|
patent.field.request_publication_date: |
Jan 11, 2024 |
А process for the preparation of а solid support for а procatalyst for olefin polymerization includes: providing а
compound R\MgX42_2 wherein: R4 is independently а linear, branched or cyclic hydrocarbyl independently selected from alkyl, alkenyl, aryl, aralkyl, or alkylaryl groups, or comЬinations thereof; Х4 is independently fluoride, chloride, bromide or iodide; and 0<z<2; and contacting the compound
R\MgX42_2 with а silane compound Si(OR5)4_п(R6)п to obtain а Mg(OR1))C\_x wherein: R1 , R5 and R6 are each independently а linear, branched or cyclic hydrocarbyl independently selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl or alkylaryl groups, or comЬinations thereof; Х1 is independently fluoride, chloride, bromide or iodide; 0<n<4; 0<z<2; and О<х<2; wherein an initiator compound, which is а ketone, а diketone, an ester, а diester, and/or а benzamide, is added during step В to obtain а solid support.