High-Temperature Interactions of C1-C4 Alkanes, Alkenes, and Alkynes with Copper Oxides as Studied by IR Spectroscopy Full article
Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
||
---|---|---|---|
Output data | Year: 1996, Volume: 70, Number: 7, Pages: 1168-1172 Pages count : 5 | ||
Authors |
|
||
Affiliations |
|
Abstract:
High-temperature interactions (at T= 473 K) of C1-C4 alkanes, alkenes, and alkynes with the surfaces of CuO and Cu2O were studied by means of IR spectroscopy. These compounds were found to undergo destructive adsorption with the predominant formation of surface formates and carboxylates. The spectral characteristics and thermal stability of the newly formed surface compounds depend on the nature of an initial compound (its saturation degree) and on the type and reduction degree of copper oxide. The rates of thermal decomposition of surface compounds were measured in situ by IR spectroscopic techniques. Direct experimental observations support the conclusion made previously that the formates are intermediate surface compounds in reactions of complete oxidation of hydrocarbons.
Cite:
Davydov A.A.
High-Temperature Interactions of C1-C4 Alkanes, Alkenes, and Alkynes with Copper Oxides as Studied by IR Spectroscopy
Russian Journal of Physical Chemistry A. 1996. V.70. N7. P.1168-1172. Scopus РИНЦ
High-Temperature Interactions of C1-C4 Alkanes, Alkenes, and Alkynes with Copper Oxides as Studied by IR Spectroscopy
Russian Journal of Physical Chemistry A. 1996. V.70. N7. P.1168-1172. Scopus РИНЦ
Original:
Давыдов А.А.
ИК-спектроскопическое изучение высокотемпературных взаимодействий алканов, алкенов и алкинов С1-С4 с оксидами меди
Журнал физической химии. 1996. Т.70. №7. С.1254-1259. WOS Scopus РИНЦ
ИК-спектроскопическое изучение высокотемпературных взаимодействий алканов, алкенов и алкинов С1-С4 с оксидами меди
Журнал физической химии. 1996. Т.70. №7. С.1254-1259. WOS Scopus РИНЦ
Dates:
Published print: | Jul 1, 1996 |
Identifiers:
Scopus | 2-s2.0-0030501367 |
Elibrary | 13235665 |
Citing:
Пока нет цитирований