Oxidation of CO and CO2 by Phosphotungstovanadic Heteropolyacids in the Presence of the Pd(II) Aquacomplex Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
---|---|---|---|
Output data | Year: 1988, Volume: 29, Number: 1 pt 2, Pages: 113-117 Pages count : 5 | ||
Tags | Carbon Dioxide; Catalysts; Chemical Reactions - Reaction Kinetics; Organometallics | ||
Authors |
|
||
Affiliations |
|
Abstract:
The kinetics of the catalytic oxidation of CO by phosphotungstovanadic heteropolyacids in aqueous solutions of PdSO4 has been studied. The rate laws are the same in the presence of two different HPAs. The first of these, PW11V, is a one-electron oxidant and the second, PW9V3, can take up to three electrons under the conditions studied. The rate data obtained showed that the HPA acts as a one-electron oxidant in the oxidation of carbon monoxide. The limiting step in the transfer of electrons from a coordinated CO molecule to a HPA occurs in an active, intermediate complex of Pd(I), apparently, as a synchronous process.
Cite:
Zhizhina E.G.
, Kuznetsova L.I.
, Matveev K.I.
Oxidation of CO and CO2 by Phosphotungstovanadic Heteropolyacids in the Presence of the Pd(II) Aquacomplex
Kinetics and Catalysis. 1988. V.29. N1 pt 2. P.113-117. WOS Scopus РИНЦ
Oxidation of CO and CO2 by Phosphotungstovanadic Heteropolyacids in the Presence of the Pd(II) Aquacomplex
Kinetics and Catalysis. 1988. V.29. N1 pt 2. P.113-117. WOS Scopus РИНЦ
Original:
Жижина Е.Г.
, Кузнецова Л.И.
, Матвеев К.И.
Окисление СО в СО2 фосфорновольфрамванадиевыми гетерополикомплексами в присутствии аквакомплекса Рd(II)
Кинетика и катализ. 1988. Т.29. №1. С.130-135. РИНЦ
Окисление СО в СО2 фосфорновольфрамванадиевыми гетерополикомплексами в присутствии аквакомплекса Рd(II)
Кинетика и катализ. 1988. Т.29. №1. С.130-135. РИНЦ
Dates:
Submitted: | Dec 24, 1986 |
Published print: | Aug 1, 1988 |
Identifiers:
Web of science | WOS:A1988Q578500001 |
Scopus | 2-s2.0-0024062170 |
Elibrary | 30934607 |