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A Multinuclear Magnetic Resonance Study of Transformations of Ruthenium(II) Nitrosyl Chloride Complexes in Aqueous Solutions Full article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Russian Journal of Inorganic Chemistry
ISSN: 0036-0236 , E-ISSN: 1531-8613
Output data Year: 2013, Volume: 58, Number: 8, Pages: 956-963 Pages count : 8 DOI: 10.1134/S003602361308007X
Authors Emelʹyanov V.A. 1,2 , Fedotov M.A. 3 , Belyaev A.V. 1 , Tkachev S.V. 1
Affiliations
1 Nikolaev Institute of Inorganic Chemistry SB RAS
2 Novosibirsk State University
3 Boreskov Institute of Catalysis SB RAS

Abstract: Aqueous solutions of ruthenium nitrosyl chloride complexes have been studied by14N, 15N, 17O, 99Ru, and 35Cl NMR. Individual complex species have been identified and the corresponding chemical shifts have been determined. The primary aquation product of the pentachloronitrosylruthenate ion is the cis-[RuNO(H2O)Cl4]− complex, which subsequently undergoes isomerization. The equilibrium constants of interconversions of ruthenium nitrosyl chloride complexes in an aqueous solution at room temperature have been estimated.
Cite: Emelʹyanov V.A. , Fedotov M.A. , Belyaev A.V. , Tkachev S.V.
A Multinuclear Magnetic Resonance Study of Transformations of Ruthenium(II) Nitrosyl Chloride Complexes in Aqueous Solutions
Russian Journal of Inorganic Chemistry. 2013. V.58. N8. P.956-963. DOI: 10.1134/S003602361308007X publication_identifier_short.wos_identifier_type publication_identifier_short.scopus_identifier_type publication_identifier_short.rinz_identifier_type
ArticleLinkType.TRANSLATED_TO_ORIGINAL: Емельянов В.А. , Федотов М.А. , Беляев А.В. , Ткачёв С.В.
Исследование превращений нитрозохлоридных комплексов рутения (II) в водных растворах методом многоядерного ЯМР
Журнал неорганической химии. 2013. Т.58. №8. С.1073-1081. DOI: 10.7868/S0044457X13080072 publication_identifier_short.rinz_identifier_type
Dates:
Submitted: Oct 30, 2012
Published print: Aug 1, 2013
Published online: Aug 8, 2013
Identifiers:
publication_identifier.wos_identifier_type WOS:000323060300014
publication_identifier.scopus_identifier_type 2-s2.0-84882237216
publication_identifier.rinz_identifier_type 20457737
publication_identifier.accession_number_identifier_type 2013:1229563
publication_identifier.chemical_accession_number_identifier_type 159:690537
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