Insights into the Borohydride Electrooxidation Reaction on Metallic Nickel from Operando FTIRS, on-line DEMS and DFT Full article
Journal |
Electrochimica Acta
ISSN: 0013-4686 , E-ISSN: 1873-3859 |
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Output data | Year: 2021, Volume: 389, Article number : 138721, Pages count : 13 DOI: 10.1016/j.electacta.2021.138721 | ||||||||||
Tags | Borohydride oxidation reaction; Polycrystalline nickel electrode; Fourier-transform infrared spectroscopy; Differential electrochemical mass spectrometry; Density functional theory calculations | ||||||||||
Authors |
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Affiliations |
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Funding (2)
1 | Russian Science Foundation | 18-73-00143 |
2 | The French National Research Agency | MobiDiC ANR-16-CE05-0009-01 |
Abstract:
Direct Borohydride Fuel Cells (DBFCs) are considered as promising power sources for portable and mobile applications. Their advantages are high theoretical energy density, and high theoretical cell voltage. Metallic Ni has recently emerged as a promising electrode material for DBFCs. In this work we combine electrochemical, operando Fourier-transform infrared spectroscopy (FTIRS), and online differential electrochemical mass spectrometry (DEMS) measurements with density functional theory (DFT) calculations to advance the understanding of the borohydride oxidation reaction on Ni.
Cite:
Oshchepkov A.G.
, Braesch G.
, Rostamikia G.
, Bonnefont A.
, Janik M.J.
, Chatenet M.
, Savinova E.R.
Insights into the Borohydride Electrooxidation Reaction on Metallic Nickel from Operando FTIRS, on-line DEMS and DFT
Electrochimica Acta. 2021. V.389. 138721 :1-13. DOI: 10.1016/j.electacta.2021.138721 WOS Scopus РИНЦ
Insights into the Borohydride Electrooxidation Reaction on Metallic Nickel from Operando FTIRS, on-line DEMS and DFT
Electrochimica Acta. 2021. V.389. 138721 :1-13. DOI: 10.1016/j.electacta.2021.138721 WOS Scopus РИНЦ
Dates:
Submitted: | Mar 4, 2021 |
Accepted: | May 29, 2021 |
Published online: | Jun 5, 2021 |
Published print: | Sep 1, 2021 |
Identifiers:
Web of science | WOS:000687283100010 |
Scopus | 2-s2.0-85108409510 |
Elibrary | 46857187 |
Chemical Abstracts | 2021:1391478 |
OpenAlex | W3166046881 |