Cyclohexanone Preparation via the Gas Phase Carboxidation of Cyclohexene by Nitrous Oxide Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Вых. Данные | Год: 2005, Том: 84, Номер: 2, Страницы: 383-388 Страниц : 6 DOI: 10.1007/s11144-005-0233-2 | ||
| Ключевые слова | Carbonyl compounds, Cyclohexanone, Cyclohexene, Nitrous oxide, Oxidation | ||
| Авторы |
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| Организации |
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Реферат:
Nitrous oxide is known to provide non-catalytic liquid phase oxidation of alkenes to carbonyl compounds (the carboxidation reaction). This paper shows that carboxidation of cyclohexene can be successfully conducted in the gas phase, too. The gas phase carboxidation is a second order reaction proceeding at 325-450oC under 3-16 bar pressure with an activation energy of 26 kcal/mol. The reaction mechanism does not involve free radical steps and leads to cyclohexanone as a main product.
Библиографическая ссылка:
Starokon E.V.
, Dubkov K.A.
, Parmon V.N.
, Panov G.I.
Cyclohexanone Preparation via the Gas Phase Carboxidation of Cyclohexene by Nitrous Oxide
Reaction Kinetics and Catalysis Letters. 2005. V.84. N2. P.383-388. DOI: 10.1007/s11144-005-0233-2 WOS Scopus РИНЦ OpenAlex CAPlusCA
Cyclohexanone Preparation via the Gas Phase Carboxidation of Cyclohexene by Nitrous Oxide
Reaction Kinetics and Catalysis Letters. 2005. V.84. N2. P.383-388. DOI: 10.1007/s11144-005-0233-2 WOS Scopus РИНЦ OpenAlex CAPlusCA
Даты:
| Поступила в редакцию: | 17 дек. 2004 г. |
| Принята к публикации: | 23 дек. 2004 г. |
| Опубликована в печати: | 1 мар. 2005 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000229264300023 |
| ≡ Scopus: | 2-s2.0-17444418328 |
| ≡ РИНЦ: | 13474708 |
| ≡ OpenAlex: | W2321023129 |
| ≡ Chemical Abstracts: | 2005:293708 |
| ≡ Chemical Abstracts (print): | 142:446851 |