Oxidation by Permanganate in Strong Alkaline Medium. Oxidation of Ethane-1,2-diol, Glycol Aldehyde, Glycollic Acid, and Glyoxylic Acid Научная публикация
| Журнал |
International Journal of Chemical Kinetics
ISSN: 0538-8066 , E-ISSN: 1097-4601 |
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| Вых. Данные | Год: 1992, Том: 24, Номер: 2, Страницы: 145-154 Страниц : 10 DOI: 10.1002/kin.550240203 | ||||
| Ключевые слова | AQUEOUS-SOLUTION; KINETICS; MECHANISM | ||||
| Авторы |
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| Организации |
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Реферат:
A study was made on the kinetics and mechanism of the reaction in aqueous solutions of 0.10 to 2.0 mol dm−3 alkaline concentrations. The substrates (S) applied were ethane-1,2-diol (ethylene glycol), glycol aldehyde, glycollic acid, and glyoxylic acid. Glycol aldehyde and glyoxylic acid were present in the form of dihydrate. In each case alkoxy anion is the reactive form and the KB constant of deprotonation can be calculated from the kinetic data. A mechanism based on electron abstraction is suggested. Manganate reacts with these substrates much slower than permanganate.
Библиографическая ссылка:
Szammer J.
, Jáky M.
, Gerasimov O.V.
Oxidation by Permanganate in Strong Alkaline Medium. Oxidation of Ethane-1,2-diol, Glycol Aldehyde, Glycollic Acid, and Glyoxylic Acid
International Journal of Chemical Kinetics. 1992. V.24. N2. P.145-154. DOI: 10.1002/kin.550240203 WOS Scopus РИНЦ CAPlusCA OpenAlex DOI (дополнительный)
Oxidation by Permanganate in Strong Alkaline Medium. Oxidation of Ethane-1,2-diol, Glycol Aldehyde, Glycollic Acid, and Glyoxylic Acid
International Journal of Chemical Kinetics. 1992. V.24. N2. P.145-154. DOI: 10.1002/kin.550240203 WOS Scopus РИНЦ CAPlusCA OpenAlex DOI (дополнительный)
Даты:
| Поступила в редакцию: | 24 янв. 1991 г. |
| Принята к публикации: | 30 июл. 1991 г. |
| Опубликована в печати: | 1 февр. 1992 г. |
| Опубликована online: | 30 сент. 2004 г. |
Идентификаторы БД:
| Web of science: | WOS:A1992HA79000002 |
| Scopus: | 2-s2.0-0026821251 |
| РИНЦ: | 31124950 |
| Chemical Abstracts: | 1992:105447 |
| Chemical Abstracts (print): | 116:105447 |
| OpenAlex: | W2117053743 |
| DOI (дополнительный): | 10.1002/chin.199222089 |