Abstract: A study was made on the kinetics and mechanism of the reaction in aqueous solutions of 0.10 to 2.0 mol dm−3 alkaline concentrations. The substrates (S) applied were ethane-1,2-diol (ethylene glycol), glycol aldehyde, glycollic acid, and glyoxylic acid. Glycol aldehyde and glyoxylic acid were present in the form of dihydrate. In each case alkoxy anion is the reactive form and the KB constant of deprotonation can be calculated from the kinetic data. A mechanism based on electron abstraction is suggested. Manganate reacts with these substrates much slower than permanganate.

Cite: Szammer J. , Jáky M. , Gerasimov O.V.
Oxidation by Permanganate in Strong Alkaline Medium. Oxidation of Ethane-1,2-diol, Glycol Aldehyde, Glycollic Acid, and Glyoxylic Acid
International Journal of Chemical Kinetics. 1992. V.24. N2. P.145-154. DOI: 10.1002/kin.550240203 WOS Scopus РИНЦ ANCAN OpenAlex DOI (extra)

Dates:

Submitted:	Jan 24, 1991
Accepted:	Jul 30, 1991
Published print:	Feb 1, 1992
Published online:	Sep 30, 2004

Identifiers:

Web of science:	WOS:A1992HA79000002
Scopus:	2-s2.0-0026821251
Elibrary:	31124950
Chemical Abstracts:	1992:105447
Chemical Abstracts (print):	116:105447
OpenAlex:	W2117053743
DOI (extra):	10.1002/chin.199222089

Citing:

DB	Citing
Web of science	46
Scopus	44
Elibrary	45
OpenAlex	33

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