Formation of Glycol Esters in the Catalytic Liquid-Phase Oxidation of Olefins. 4. State of Cupric Ions and Iodine Molecules under Conditions of the Catalytic-Oxidation of Propylene to Propylene-Glycol Acetates | Sciact - CRIS-system of Boreskov Institute of Catalysis

Formation of Glycol Esters in the Catalytic Liquid-Phase Oxidation of Olefins. 4. State of Cupric Ions and Iodine Molecules under Conditions of the Catalytic-Oxidation of Propylene to Propylene-Glycol Acetates Full article

Journal

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Output data

Year: 1983, Volume: 24, Number: 1, Pages: 42-49 Pages count : 8

Authors

Gusevskaya E.V. ¹ , Likholobov V.A. ¹ , Talsi E.P. ¹ , Ermakov Y.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch U.S.S.R. Academy of Sciences

Complexation processes occurring during the title oxidation in HOAc in the presence of LiCl were studied by electronic and ESR spectroscopy. The I2 is activated toward the olefin by complexation with Cu chlorides to form CuCl2·I2 and possibly CuCl·CuCl2·I2.

Gusevskaya E.V. , Likholobov V.A. , Talsi E.P. , Ermakov Y.I.
Formation of Glycol Esters in the Catalytic Liquid-Phase Oxidation of Olefins. 4. State of Cupric Ions and Iodine Molecules under Conditions of the Catalytic-Oxidation of Propylene to Propylene-Glycol Acetates
Kinetics and Catalysis. 1983. V.24. N1. P.42-49. WOS РИНЦ

Гусевская Е.В. , Лихолобов В.А. , Талзи Е.П. , Ермаков Ю.И.
Изучение реакций образования эфиров гликолей при каталитическом жидкофазном окислении олефинов. IV. Изучение состояния ионов меди (II) и молекул иода в условиях каталитической реакции окисления пропилена до ацетатов пропиленгликоля
Кинетика и катализ. 1983. Т.24. №1. С.53-60. РИНЦ ANCAN

Submitted:	Jul 20, 1981
Published print:	Jan 1, 1983

Web of science:	WOS:A1983RK36300009
Elibrary:	30602873

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