Influence of an Interaction of PdCl2 with Carbon Support on State and Catalytic Properties of Pd/C Catalysts Научная публикация
| Конференция |
Scientific Bases for the Preparation of Heterogeneous Catalysts : 6th International Symposium 05-08 сент. 1994 , Louvain-La-Neuve |
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| Сборник | Preparation of Catalysts VI. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Sixth International Symposium, 5-8 September 1994, Louvain-La-Neuve Сборник, 1995. 1182 c. |
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| Журнал |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Вых. Данные | Год: 1995, Том: 91, Страницы: 977-987 Страниц : 11 DOI: 10.1016/S0167-2991(06)81841-0 | ||
| Авторы |
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| Организации |
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Реферат:
Influence of substructure, texture and chemical properties of carbon supports at each step of the formation of Pd/C catalysts was studied for one of the conventional methods of catalyst manufacture involving adsorption of H2PdCl4 on the support followed by drying and reduction procedures. The adsorption was found to be accompanied by the formation of mononuclear π-complexes of PdCl2 with >C=C< fragments of the support surface. Drying step gives rise to PdCl2 clusters that remain the coordination with these fragments. The consequence of this strong interaction and carbon matrix imperfection is that the surface of the metallic particles formed at the reduction step appears to be partially or completely blocked by other carbon networks.
Библиографическая ссылка:
Simonov P.A.
, Moroz E.M.
, Chuvilin A.L.
, Kolomiichuk V.N.
, Boronin A.I.
, Likholobov V.A.
Influence of an Interaction of PdCl2 with Carbon Support on State and Catalytic Properties of Pd/C Catalysts
В сборнике Preparation of Catalysts VI. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Sixth International Symposium, 5-8 September 1994, Louvain-La-Neuve. 1995. – C.977-987. DOI: 10.1016/S0167-2991(06)81841-0 WOS Scopus РИНЦ CAPlusCA OpenAlex
Influence of an Interaction of PdCl2 with Carbon Support on State and Catalytic Properties of Pd/C Catalysts
В сборнике Preparation of Catalysts VI. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Sixth International Symposium, 5-8 September 1994, Louvain-La-Neuve. 1995. – C.977-987. DOI: 10.1016/S0167-2991(06)81841-0 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 янв. 1995 г. |
| Опубликована online: | 2 сент. 2007 г. |
Идентификаторы БД:
| Web of science: | WOS:A1995BE35H00100 |
| Scopus: | 2-s2.0-0001482465 |
| РИНЦ: | 26590769 |
| Chemical Abstracts: | 1995:799695 |
| Chemical Abstracts (print): | 123:267551 |
| OpenAlex: | W1524772533 |