Influence of an Interaction of PdCl2 with Carbon Support on State and Catalytic Properties of Pd/C Catalysts Full article
| Conference |
Scientific Bases for the Preparation of Heterogeneous Catalysts : 6th International Symposium 05-08 Sep 1994 , Louvain-La-Neuve |
||
|---|---|---|---|
| Source | Preparation of Catalysts VI. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Sixth International Symposium, 5-8 September 1994, Louvain-La-Neuve Compilation, 1995. 1182 c. |
||
| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
||
| Output data | Year: 1995, Volume: 91, Pages: 977-987 Pages count : 11 DOI: 10.1016/S0167-2991(06)81841-0 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
Influence of substructure, texture and chemical properties of carbon supports at each step of the formation of Pd/C catalysts was studied for one of the conventional methods of catalyst manufacture involving adsorption of H2PdCl4 on the support followed by drying and reduction procedures. The adsorption was found to be accompanied by the formation of mononuclear π-complexes of PdCl2 with >C=C< fragments of the support surface. Drying step gives rise to PdCl2 clusters that remain the coordination with these fragments. The consequence of this strong interaction and carbon matrix imperfection is that the surface of the metallic particles formed at the reduction step appears to be partially or completely blocked by other carbon networks.
Cite:
Simonov P.A.
, Moroz E.M.
, Chuvilin A.L.
, Kolomiichuk V.N.
, Boronin A.I.
, Likholobov V.A.
Influence of an Interaction of PdCl2 with Carbon Support on State and Catalytic Properties of Pd/C Catalysts
In compilation Preparation of Catalysts VI. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Sixth International Symposium, 5-8 September 1994, Louvain-La-Neuve. 1995. – C.977-987. DOI: 10.1016/S0167-2991(06)81841-0 WOS Scopus РИНЦ OpenAlex ANCAN
Influence of an Interaction of PdCl2 with Carbon Support on State and Catalytic Properties of Pd/C Catalysts
In compilation Preparation of Catalysts VI. Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the Sixth International Symposium, 5-8 September 1994, Louvain-La-Neuve. 1995. – C.977-987. DOI: 10.1016/S0167-2991(06)81841-0 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Published print: | Jan 1, 1995 |
| Published online: | Sep 2, 2007 |
Identifiers:
| ≡ Web of science: | WOS:A1995BE35H00100 |
| ≡ Scopus: | 2-s2.0-0001482465 |
| ≡ Elibrary: | 26590769 |
| ≡ OpenAlex: | W1524772533 |
| ≡ Chemical Abstracts: | 1995:799695 |
| ≡ Chemical Abstracts (print): | 123:267551 |