Perchloroethylene Hydrofluorination in the Presence of a Chromium–Magnesium Catalyst | Sciact - CRIS-система Института катализа

Perchloroethylene Hydrofluorination in the Presence of a Chromium–Magnesium Catalyst Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2008, Том: 49, Номер: 5, Страницы: 663-666 Страниц : 4 DOI: 10.1134/S0023158408050108

Ключевые слова

Product Selectivity; Reaction Rate Increase; Silochrom; Chromium Chloride; Perchloroethylene

Авторы

Zirka A.A. ¹ , Reshetnikov S.I. ¹

Организации

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Science, Novosibirsk, 630090, Russia

The gas-phase hydrofluorination of perchloroethylene into pentafluoroethane (R-125) at T = 330–390°C and P = 0.4 MPa in the presence of a chromium-magnesium catalyst is reported. The reaction rate under these conditions is described by a first-order equation. A hydrofluorination scheme including main product and by-product formation routes is deduced from the observed dependences of particular product selectivities on the total perchloroethylene conversion.

Zirka A.A. , Reshetnikov S.I.
Perchloroethylene Hydrofluorination in the Presence of a Chromium–Magnesium Catalyst
Kinetics and Catalysis. 2008. V.49. N5. P.663-666. DOI: 10.1134/S0023158408050108 WOS Scopus РИНЦ CAPlusCA OpenAlex

Зирка А.А. , Решетников С.И.
Исследование реакции гидрофторирования перхлорэтилена в присутствии хроммагниевого катализатора
Кинетика и катализ. 2008. Т.49. №5. С.694-697. РИНЦ

Поступила в редакцию:	10 мая 2007 г.
Опубликована в печати:	1 сент. 2008 г.
Опубликована online:	30 сент. 2008 г.

Web of science:	WOS:000259698000010
Scopus:	2-s2.0-53249156454
РИНЦ:	13593417
Chemical Abstracts:	2008:1175946
Chemical Abstracts (print):	149:576086
OpenAlex:	W2001168818

БД	Цитирований
Web of science	5
Scopus	5
РИНЦ	3
OpenAlex	5