Perchloroethylene Hydrofluorination in the Presence of a Chromium–Magnesium Catalyst Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||
|---|---|---|---|
| Output data | Year: 2008, Volume: 49, Number: 5, Pages: 663-666 Pages count : 4 DOI: 10.1134/S0023158408050108 | ||
| Tags | Product Selectivity; Reaction Rate Increase; Silochrom; Chromium Chloride; Perchloroethylene | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The gas-phase hydrofluorination of perchloroethylene into pentafluoroethane (R-125) at T = 330–390°C and P = 0.4 MPa in the presence of a chromium-magnesium catalyst is reported. The reaction rate under these conditions is described by a first-order equation. A hydrofluorination scheme including main product and by-product formation routes is deduced from the observed dependences of particular product selectivities on the total perchloroethylene conversion.
Cite:
Zirka A.A.
, Reshetnikov S.I.
Perchloroethylene Hydrofluorination in the Presence of a Chromium–Magnesium Catalyst
Kinetics and Catalysis. 2008. V.49. N5. P.663-666. DOI: 10.1134/S0023158408050108 WOS Scopus РИНЦ OpenAlex ANCAN
Perchloroethylene Hydrofluorination in the Presence of a Chromium–Magnesium Catalyst
Kinetics and Catalysis. 2008. V.49. N5. P.663-666. DOI: 10.1134/S0023158408050108 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Зирка А.А.
, Решетников С.И.
Исследование реакции гидрофторирования перхлорэтилена в присутствии хроммагниевого катализатора
Кинетика и катализ. 2008. Т.49. №5. С.694-697. РИНЦ
Исследование реакции гидрофторирования перхлорэтилена в присутствии хроммагниевого катализатора
Кинетика и катализ. 2008. Т.49. №5. С.694-697. РИНЦ
Dates:
| Submitted: | May 10, 2007 |
| Published print: | Sep 1, 2008 |
| Published online: | Sep 30, 2008 |
Identifiers:
| ≡ Web of science: | WOS:000259698000010 |
| ≡ Scopus: | 2-s2.0-53249156454 |
| ≡ Elibrary: | 13593417 |
| ≡ OpenAlex: | W2001168818 |
| ≡ Chemical Abstracts: | 2008:1175946 |
| ≡ Chemical Abstracts (print): | 149:576086 |