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Structure and Acid-Base Properties of Hexaaluminates Научная публикация

Журнал Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Вых. Данные Год: 2008, Том: 93, Номер: 2, Страницы: 375-387 Страниц : 13 DOI: 10.1007/s11144-008-5300-z
Ключевые слова Acid-base properties, Hexaaluminate, XRD
Авторы Bukhtiyarova Marina V. 1 , Ivanova Aleksandra S. 1 , Plyasova Lyudmila M. 1 , Litvak Galina S. 1 , Budneva Anna A. 1 , Paukshtis Evgenii A. 1
Организации
1 Boreskov Institute of Catalysis

Реферат: Hexaaluminates SrAl12O19, BaAl12O19 and LaAl11O18 were prepared by co-precipitation of soluble nitrates of Sr, Ba, or La and Al using NH4HCO3 as a precipitating agent with subsequent calcination at 700–1400°C. The samples were characterized by adsorption methods, thermal analysis (TA and DTG), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy of adsorbed probe molecules (CO and CDCl3). It was shown that calcination at 1200°C resulted in the formation of single-phase hexaaluminates in all the samples except for LaAl11O18, where an additional phase was found. The specific surface area of the samples was obtained in the range 16–22 m2/g. After the treatment at comparable conditions, the total concentrations of both surface Lewis acid sites and basic sites were found to increase in the series: BaAl12O19 < SrAl12O19 < LaAl11O18. However, the strongest basic sites were detected on the surface of BaAl12O19.
Библиографическая ссылка: Bukhtiyarova M.V. , Ivanova A.S. , Plyasova L.M. , Litvak G.S. , Budneva A.A. , Paukshtis E.A.
Structure and Acid-Base Properties of Hexaaluminates
Reaction Kinetics and Catalysis Letters. 2008. V.93. N2. P.375-387. DOI: 10.1007/s11144-008-5300-z WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 19 февр. 2008 г.
Принята к публикации: 21 февр. 2008 г.
Опубликована в печати: 1 апр. 2008 г.
Опубликована online: 27 нояб. 2008 г.
Идентификаторы БД:
Web of science: WOS:000255003000024
Scopus: 2-s2.0-57249086443
РИНЦ: 13581897
Chemical Abstracts: 2008:561955
Chemical Abstracts (print): 150:549003
OpenAlex: W2039716260
Цитирование в БД:
БД Цитирований
Web of science 7
Scopus 7
РИНЦ 7
OpenAlex 11
Альметрики: