Investigation of H2S Oxidation by Oxygen on Oxide Catalysts in Sulfur Condensation Conditions Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 1998, Том: 64, Номер: 1, Страницы: 129-138 Страниц : 9 DOI: 10.1007/BF02475380 | ||
Ключевые слова | Catalytic activity, H2S, Oscillations, Oxidation, Oxide catalysts, Oxygen | ||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Российский фонд фундаментальных исследований | 96-03-33660 |
Реферат:
H2S oxidation with oxygen has been studied on three industrial oxide catalysts (Fe−Cr−Zn, Cu−Cr−Al, V−Ti−Al). Thermodynamically possible changes in the composition of the catalysts have been evaluated. Regularities determining deep or partial oxidation of H2S have been found. Deep oxidation is connected to the presence of active oxygen on the catalyst surface; its removal results in a decrease of activity and increase of the sulfur selectivity. Oscillations caused by periodic adsorption-desorption of sulfur on the catalyst surface have been observed on the most active V−Ti−Al catalysts in oxygen excess.
Библиографическая ссылка:
Kovalenko O.N.
, Kundo N.N.
, Novopashina V.M.
, Khanaev V.M.
Investigation of H2S Oxidation by Oxygen on Oxide Catalysts in Sulfur Condensation Conditions
Reaction Kinetics and Catalysis Letters. 1998. V.64. N1. P.129-138. DOI: 10.1007/BF02475380 WOS Scopus РИНЦ CAPlusCA OpenAlex
Investigation of H2S Oxidation by Oxygen on Oxide Catalysts in Sulfur Condensation Conditions
Reaction Kinetics and Catalysis Letters. 1998. V.64. N1. P.129-138. DOI: 10.1007/BF02475380 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: | 26 мар. 1997 г. |
Принята к публикации: | 21 апр. 1997 г. |
Опубликована в печати: | 1 мая 1998 г. |
Идентификаторы БД:
Web of science: | WOS:000074047100019 |
Scopus: | 2-s2.0-0000665517 |
РИНЦ: | 13287441 |
Chemical Abstracts: | 1998:478601 |
Chemical Abstracts (print): | 129:165460 |
OpenAlex: | W2073133680 |