Investigation of H2S Oxidation by Oxygen on Oxide Catalysts in Sulfur Condensation Conditions Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||
|---|---|---|---|
| Output data | Year: 1998, Volume: 64, Number: 1, Pages: 129-138 Pages count : 9 DOI: 10.1007/BF02475380 | ||
| Tags | Catalytic activity, H2S, Oscillations, Oxidation, Oxide catalysts, Oxygen | ||
| Authors |
|
||
| Affiliations |
|
Funding (1)
| 1 | Russian Foundation for Basic Research | 96-03-33660 |
Abstract:
H2S oxidation with oxygen has been studied on three industrial oxide catalysts (Fe−Cr−Zn, Cu−Cr−Al, V−Ti−Al). Thermodynamically possible changes in the composition of the catalysts have been evaluated. Regularities determining deep or partial oxidation of H2S have been found. Deep oxidation is connected to the presence of active oxygen on the catalyst surface; its removal results in a decrease of activity and increase of the sulfur selectivity. Oscillations caused by periodic adsorption-desorption of sulfur on the catalyst surface have been observed on the most active V−Ti−Al catalysts in oxygen excess.
Cite:
Kovalenko O.N.
, Kundo N.N.
, Novopashina V.M.
, Khanaev V.M.
Investigation of H2S Oxidation by Oxygen on Oxide Catalysts in Sulfur Condensation Conditions
Reaction Kinetics and Catalysis Letters. 1998. V.64. N1. P.129-138. DOI: 10.1007/BF02475380 WOS Scopus РИНЦ OpenAlex ANCAN
Investigation of H2S Oxidation by Oxygen on Oxide Catalysts in Sulfur Condensation Conditions
Reaction Kinetics and Catalysis Letters. 1998. V.64. N1. P.129-138. DOI: 10.1007/BF02475380 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
| Submitted: | Mar 26, 1997 |
| Accepted: | Apr 21, 1997 |
| Published print: | May 1, 1998 |
Identifiers:
| ≡ Web of science: | WOS:000074047100019 |
| ≡ Scopus: | 2-s2.0-0000665517 |
| ≡ Elibrary: | 13287441 |
| ≡ OpenAlex: | W2073133680 |
| ≡ Chemical Abstracts: | 1998:478601 |
| ≡ Chemical Abstracts (print): | 129:165460 |