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Preferential Methanation of CO using Halogen-Doped (F, Cl, Br) Ceria-Supported Nickel Catalysts Full article

Journal Energy Technology
ISSN: 2194-4288
Output data Year: 2017, Volume: 5, Number: 9, Pages: 1522-1525 Pages count : 4 DOI: 10.1002/ente.201700088
Tags carbon monoxide, ceria, fuel cells, heterogeneous catalysis, methanation
Authors Konishcheva Margarita V. 1,2 , Potemkin Dmitriy I. 1,2 , Snytnikov Pavel V. 1,2 , Pakharukova Vera P. 1 , Sobyanin Vladimir A. 1
Affiliations
1 Laboratory of Catalytic Processes in Fuel Cells, Boreskov Institute of Catalysis, Pr. ak. Lavrentieva, 5, Novosibirsk, 630090 (Russian Federation)
2 Laboratory of Energy-Efficient Catalytic Processes, Novosibirsk State University, Pirogova Str., 2, Novosibirsk, 630090 (Russian Federation)

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0011

Abstract: Halogen-doped Ni(F)/CeO2, Ni(Cl)/CeO2, and Ni(Br)/CeO2 catalysts were prepared by treating halogen-free Ni/CeO2 with aqueous solutions of NH4F, NH4Cl, and NH4Br, respectively. It was demonstrated that the halogen dopants had distinct effects on the catalyst properties for the CO preferential methanation using realistic reformate gas: fluorine did not change catalytic activity, chlorine inhibited CO2 methanation activity and provided high selectivity towards CO methanation, and bromine completely inhibited both the CO and CO2 methanation activity.
Cite: Konishcheva M.V. , Potemkin D.I. , Snytnikov P.V. , Pakharukova V.P. , Sobyanin V.A.
Preferential Methanation of CO using Halogen-Doped (F, Cl, Br) Ceria-Supported Nickel Catalysts
Energy Technology. 2017. V.5. N9. P.1522-1525. DOI: 10.1002/ente.201700088 WOS Scopus РИНЦ OpenAlex ANCAN
Dates:
Submitted: Feb 10, 2017
Accepted: Feb 13, 2017
Published online: Mar 22, 2017
Published print: Sep 1, 2017
Identifiers:
≡ Web of science: WOS:000410137900004
≡ Scopus: 2-s2.0-85017152769
≡ Elibrary: 31028508
≡ OpenAlex: W2587865191
≡ Chemical Abstracts: 2017:1471774
≡ Chemical Abstracts (print): 171:76034
Citing:
≡ Web of science 11 Сбор данных от 06.02.2026
≡ Scopus 11 Сбор данных от 08.02.2026
≡ OpenAlex 11 Сбор данных от 08.02.2026
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