Catalytic Asymmetric Oxidations Using Molecular Oxygen | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Asymmetric Oxidations Using Molecular Oxygen Review

Journal

Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837

Output data

Year: 2018, Volume: 87, Number: 9, Pages: 821-830 Pages count : 10 DOI: 10.1070/rcr4825

Tags

Enantioselective alpha-hydroxylation; ketoiminato manganese(III) complexes; phase-transfer catalysts; aerobic epoxidation; unfunctionalized olefins; efficient catalysts; ketones; cyclobutanones; oxindoles; sulfides

Authors

Ottenbacher Roman V. ^1,2 , Talsi Evgenii P. ^1,2 , Bryliakov Konstantin P. ^1,2

Affiliations

1	Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russian Federation
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk

Funding (2)

1	Russian Foundation for Basic Research	16-29-10666
2	Ministry of Science and Higher Education of the Russian Federation	ГЗ-2017-2020

Catalytic enantioselective oxygen transfer reactions have been a long-standing goal of synthetic chemistry. The use of molecular oxygen in these oxidations has engaged significant research efforts for decades. The present review considers the state of the art of aerobic asymmetric oxidations mediated by chiral organocatalysts and transition metal catalysts, occurring with formation of new C–O bonds, i.e. oxygenations. The milestones and limitations of existing approaches are discussed, with focus on catalyst design and catalytic performance.

Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Catalytic Asymmetric Oxidations Using Molecular Oxygen
Russian Chemical Reviews. 2018. V.87. N9. P.821-830. DOI: 10.1070/rcr4825 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Mar 27, 2018
Published online:	Sep 3, 2018
Published print:	Sep 30, 2018

Web of science:	WOS:000443383600001
Scopus:	2-s2.0-85052848680
Elibrary:	35268633
Chemical Abstracts:	2018:2306610
OpenAlex:	W2806733926

DB	Citing
Web of science	14
Scopus	15
OpenAlex	16