A Large Anisotropic Plasticity of L-Leucinium Hydrogen Maleate Preserved at Cryogenic Temperatures | Sciact - CRIS-system of Boreskov Institute of Catalysis

A Large Anisotropic Plasticity of L-Leucinium Hydrogen Maleate Preserved at Cryogenic Temperatures Full article

Journal

Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
ISSN: 2052-5192 , E-ISSN: 2052-5206

Output data

Year: 2019, Volume: 75 B, Number: 2, Pages: 143-151 Pages count : 9 DOI: 10.1107/s2052520619000441

Tags

plastic crystals; low temperature; hydrogen bonds; intermolecular interactions

Authors

Arkhipov S.G. ^1,2,3 , Losev E.A. ^1,2,3 , Nguyen T.T. ¹ , Rychkov D.A. ^1,2 , Boldyreva E.V. ^1,3

Affiliations

1	Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russian Federation
2	Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk, 630128, Russian Federation
3	Boreskov Institute of Catalysis SB RAS, Lavrentiev Ave. 5, Novosibirsk, 630090, Russian Federation

Funding (4)

1	Russian Foundation for Basic Research	16-33-60089 (АААА-А16-116021550280-1)
2	Ministry of Science and Higher Education of the Russian Federation	0239-2019-0003
3	Russian Foundation for Basic Research	18-43-543004 (АААА-А18-118061890006-6)
4	The Ministry of Education and Science of the Russian Federation	Проект 5-100

L-Leucinium hydrogen maleate crystals are very plastic at ambient conditions. Here it is shown that this plasticity is preserved at least down to 77 K. The structural changes in the temperature range 293–100 K were followed in order to rationalize the large anisotropic plasticity in this compound. To the best of our knowledge, this is the first reported example of an organic compound remaining so plastic at cryogenic conditions.

Arkhipov S.G. , Losev E.A. , Nguyen T.T. , Rychkov D.A. , Boldyreva E.V.
A Large Anisotropic Plasticity of L-Leucinium Hydrogen Maleate Preserved at Cryogenic Temperatures
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2019. V.75 B. N2. P.143-151. DOI: 10.1107/s2052520619000441 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Dec 6, 2018
Accepted:	Jan 8, 2019
Published online:	Mar 13, 2019
Published print:	Apr 1, 2019

Web of science:	WOS:000463912400005
Scopus:	2-s2.0-85063033352
Elibrary:	45554420
Chemical Abstracts:	2019:733580
OpenAlex:	W2921647223

DB	Citing
Scopus	16
Web of science	16
Elibrary	17
OpenAlex	17