Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks | Sciact - CRIS-system of Boreskov Institute of Catalysis

Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks Full article

Journal

Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691

Output data

Year: 2020, Volume: 20, Number: 11, Pages: 1297-1313 Pages count : 18 DOI: 10.1002/tcr.202000072, 10.1002/tcr.202081101

Tags

Porous Coordination Polymers, Metal-Organic Frameworks, Proton Conductivity, Proton Dynamics, Conduction Mechanism

Authors

Kolokolov Daniil I. ^1,2 , Lim Dae‐Woon ³ , Kitagawa Hiroshi ⁴

Affiliations

1	Siberian Branch of Russian Academy of Sciences, Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2	Department of Physics, Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090, Russia
3	Department of Chemistry and Medical Chemistry, Yonsei University, 1 Yonseidae-gil, Wonju, Gangwon-do, 26493, Korea
4	Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan

Funding (3)

1	Japan Science and Technology Agency	JPMJAC1501
2	Federal Agency for Scientific Organizations	0303-2016-0003
3	Russian Foundation for Basic Research	20-33-70141

Proton conductivity has been traditionally investigated with various materials such as organic polymers, metal oxides, and other inorganic and organic compounds because of their potential application in the electrochemical devices. In particular, during the last decade, crystalline porous coordination polymers (PCPs) or metal‐organic frameworks (MOFs) have received considerable attention in recent years, as solid‐state proton conductors (SSPCs). To date, proton‐conductive MOFs have achieved high performance in proton conductivity (>10−2 S cm−1) with rational design strategies. In addition, there are dedicated efforts to define the conduction pathway and mechanism using various experimental tools. In this review, we focus on the characterization of proton conductivity and molecular dynamics in hydrated MOFs, with selected examples to provide an understanding of the overall conduction mechanism.

Kolokolov D.I. , Lim D. , Kitagawa H.
Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks
Chemical Record. 2020. V.20. N11. P.1297-1313. DOI: 10.1002/tcr.202000072, 10.1002/tcr.202081101 WOS Scopus РИНЦ ANCAN PMID OpenAlex

Submitted:	Jun 18, 2020
Accepted:	Aug 24, 2020
Published online:	Sep 21, 2020
Published print:	Nov 1, 2020

Web of science:	WOS:000571436700001
Scopus:	2-s2.0-85091236777
Elibrary:	45313139
Chemical Abstracts:	2020:1894853
Chemical Abstracts (print):	179:18868
PMID:	32959508
OpenAlex:	W3087131247

DB	Citing
Scopus	71
Web of science	79
Elibrary	62
OpenAlex	71