Advanced Green Approaches for the Synthesis of NiCu-Containing Catalysts for the Hydrodeoxygenation of Anisole Full article
| Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Output data | Year: 2020, Volume: 379, Pages: 262-271 Pages count : 10 DOI: 10.1016/j.cattod.2020.09.006 | ||
| Tags | Heterogeneous catalysts; Bio-oil; Hydrodeoxygenation; Green chemistry; Supercritical antisolvent | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 18-29-06022 |
| 2 | Ministry of Science and Higher Education of the Russian Federation | 075-15-2019-1876 |
Abstract:
NiCu-containing catalysts stabilized by SiO2 with a different metals ratio are prepared via the «green» supercritical antisolvent (SAS) precipitation method. Obtained catalysts are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and CO adsorption. The addition of water and a silica sol into precursor solution allows us to obtain highly loaded (70 wt. % of metals) dispersed metal catalysts with a Ni1-xCux solid solution structure without phase separation into individual metals. These heterogeneous catalysts are used for hydrodeoxygenation of anisole – a model compound of pyrolysis liquid. The main product of the hydrodeoxygenation process over prepared catalysts was cyclohexane.
Cite:
Nesterov N.S.
, Smirnov A.A.
, Pakharukova V.P.
, Yakovlev V.A.
, Martyanov O.N.
Advanced Green Approaches for the Synthesis of NiCu-Containing Catalysts for the Hydrodeoxygenation of Anisole
Catalysis Today. 2020. V.379. P.262-271. DOI: 10.1016/j.cattod.2020.09.006 WOS Scopus РИНЦ AN OpenAlex
Advanced Green Approaches for the Synthesis of NiCu-Containing Catalysts for the Hydrodeoxygenation of Anisole
Catalysis Today. 2020. V.379. P.262-271. DOI: 10.1016/j.cattod.2020.09.006 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Jan 28, 2020 |
| Accepted: | Sep 1, 2020 |
| Published print: | Sep 1, 2020 |
| Published online: | Sep 16, 2020 |
Identifiers:
| Web of science: | WOS:000687320400002 |
| Scopus: | 2-s2.0-85091686960 |
| Elibrary: | 45301234 |
| Chemical Abstracts: | 2020:1960143 |
| OpenAlex: | W3087294454 |